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迈向碳中和与循环经济:德国某城市污水处理厂中强化沼气生产与从污泥脱水液中回收养分的创新组合。

Towards carbon neutrality and circular economy: an innovative combination of enhanced biogas production and nutrient recovery from sludge dewatering liquor at a municipal wastewater treatment plant in Germany.

机构信息

Kompetenzzentrum Wasser Berlin gGmbH, Grunewaldstraße 61-62, Berlin 10825, Germany E-mail:

Kompetenzzentrum Wasser Berlin gGmbH, Grunewaldstraße 61-62, Berlin 10825, Germany.

出版信息

Water Sci Technol. 2024 Aug;90(3):680-695. doi: 10.2166/wst.2024.247. Epub 2024 Jul 20.

Abstract

An innovative circular economy (CE) system was implemented at the wastewater treatment plant (WWTP) in Brunswick. The performance of the CE system was evaluated for 4 years: the thermal pressure hydrolysis enhanced the methane production by 18% and increased the digestate dewaterability by 14%. Refractory COD formed in thermal hydrolysis and increased the COD concentration in the WWTP effluent by 4 mg L while still complying with the legal threshold. Struvite production reached high phosphorus recovery rates of >80% with a Mg:P molar ratio ≥0.8. Nitrogen was successfully recovered as ammonium sulfate with high recovery rates of 85-97%. The chemical analyses of secondary fertilizers showed a low pollutant content, posing low risks to soil and groundwater ecosystems. The total carbon footprint of the WWTP decreased due to enhanced biogas production, the recovery of renewable fertilizers and a further reduction of nitrous oxide emissions. Using green energy will be crucial to reach carbon neutrality for the entire WWTP.

摘要

在不伦瑞克的污水处理厂(WWTP)实施了一种创新的循环经济(CE)系统。该 CE 系统的性能已评估了 4 年:热压水解将甲烷产量提高了 18%,并将消化物的脱水能力提高了 14%。热水解过程中形成了难降解 COD,使 WWTP 出水的 COD 浓度增加了 4mg/L,但仍符合法定阈值。通过生成鸟粪石,实现了高磷回收率,超过 80%,Mg:P 摩尔比≥0.8。氮作为硫酸铵成功回收,回收率高达 85-97%。二次肥料的化学分析表明,其污染物含量低,对土壤和地下水生态系统的风险低。由于沼气产量增加、可再生肥料的回收以及氧化亚氮排放量的进一步减少,WWTP 的总碳足迹减少。使用绿色能源对于 WWTP 实现碳中和至关重要。

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