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掺杂铜的合成CaBO纳米颗粒的热释光和光激发发光特性研究。

Study of Thermoluminescence and Optically Stimulated Luminescence Properties of Synthesised CaBO Nanoparticles Doped with Copper.

作者信息

Hemam Ritesh, Singh L Robindro, Singh Sh Dorendrajit

机构信息

Department of Physics, Kumbi College, Kumbi, Manipur, 795133, India.

Department of Nanotechnology, North Eastern Hill University, Shillong, 793022, India.

出版信息

J Fluoresc. 2025 Jun;35(6):4901-4909. doi: 10.1007/s10895-024-03893-5. Epub 2024 Aug 14.

DOI:10.1007/s10895-024-03893-5
PMID:39141273
Abstract

CaBO nanorods doped with different concentrations of Cu were prepared by using co-precipitation method. The recorded Thermoluminescence (TL) and Optically stimulated luminescence (OSL) of CaBO:Cu samples for different concentrations of Cu irradiated with 6 Gy of X-Ray shows that 0.05 at.wt% of Cu concentrations have higher sensitivity. The TL and OSL kinetic parameters of glow curves were evaluated using "tgcd" and conventional fitting methods. The TL glow curve of the CaBO:Cu have three individual glow peaks with maximum peak temperatures at 404.50, 453.04 and 484.02 K respectively. The OSL glow curves of the CaBO:Cu nanoparticles follow non-first order kinetics which can be fitted with the sum of two first order decay curves.

摘要

采用共沉淀法制备了掺杂不同浓度铜的CaBO纳米棒。对不同铜浓度的CaBO:Cu样品在6 Gy X射线辐照下记录的热释光(TL)和光激发发光(OSL)表明,0.05 at.wt%的铜浓度具有更高的灵敏度。使用“tgcd”和传统拟合方法评估了发光曲线的TL和OSL动力学参数。CaBO:Cu的TL发光曲线有三个单独的发光峰,最大峰温分别为404.50、453.04和484.02 K。CaBO:Cu纳米颗粒的OSL发光曲线遵循非一级动力学,可由两条一级衰减曲线的总和拟合。

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本文引用的文献

1
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Appl Radiat Isot. 2024 Apr;206:111202. doi: 10.1016/j.apradiso.2024.111202. Epub 2024 Jan 30.
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Optically stimulated luminescence in LiCaAlF6:Eu2+ phosphor.LiCaAlF6:Eu2+荧光粉中的光激发发光
Luminescence. 2015 Sep;30(6):878-82. doi: 10.1002/bio.2836. Epub 2015 Jan 26.
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Deconvolution and simulation of thermoluminescence glow curves with Mathcad.使用Mathcad对热释光发光曲线进行反卷积和模拟。
Radiat Prot Dosimetry. 2013 Sep;156(3):261-7. doi: 10.1093/rpd/nct072. Epub 2013 Mar 24.