Xiong Hao, Shao Ligang, Cao Yuan, Wang Guishi, Wang Ruifeng, Mei Jiaoxu, Liu Kun, Gao Xiaoming
College of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei, Anhui 230026, China.
Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei, Anhui 230037, China.
ACS Sens. 2024 Sep 27;9(9):4906-4914. doi: 10.1021/acssensors.4c01514. Epub 2024 Aug 16.
Owing to the overlapping and cross-interference of absorption lines in multicomponent gases, the simultaneous measurement of such gases via laser absorption spectroscopy frequently necessitates the use of supplementary pressure sensors to distinguish the spectral lines. Alternatively, it requires multiple lasers combined with time-division multiplexing to independently scan the absorption peaks of each gas, thereby preventing interference from other gases. This inevitably escalates both the cost of the system and the complexity of the gas pathway. In response to these challenges, a mid-infrared sensor employing a neural network-based decoupling algorithm for aliasing spectral is developed, enabling the simultaneous detection of methane(CH), water vapor(HO), and ethane(CH). The sensor system underwent evaluation in a controlled laboratory environment. Allan deviation analysis revealed that the minimum detection limits for CH,HO, and CH were 6.04, 118.44, and 1 ppb, respectively, with an averaging time of 3 s. The performance of the proposed sensor demonstrates that the aliasing spectral decoupling algorithm based on neural network combined with wavelength-modulated spectroscopy technology has the advantages of high sensitivity, low cost and low complexity, showing its potential for simultaneous detection of multicomponent trace gases in various fields.
由于多组分气体中吸收线的重叠和交叉干扰,通过激光吸收光谱法同时测量此类气体时,常常需要使用辅助压力传感器来区分光谱线。或者,它需要多个激光器与时分复用相结合,以独立扫描每种气体的吸收峰,从而防止其他气体的干扰。这不可避免地增加了系统成本和气路的复杂性。针对这些挑战,开发了一种采用基于神经网络的去耦算法来消除光谱混叠的中红外传感器,能够同时检测甲烷(CH)、水蒸气(HO)和乙烷(CH)。该传感器系统在可控的实验室环境中进行了评估。阿伦偏差分析表明,CH、HO和CH的最低检测限分别为6.04、118.44和1 ppb,平均时间为3秒。所提出传感器的性能表明,基于神经网络的光谱混叠去耦算法与波长调制光谱技术相结合,具有灵敏度高、成本低和复杂度低的优点,显示出其在各个领域同时检测多组分痕量气体的潜力。