Shirali Mahdi, Rouhani Shohre, Gharanjig Kamaladin, Mirhashemi Fatemeh
Department of Chemistry Laboratory of Oilfields in Southern Iran (NISOC), Ahvaz, Iran.
Department of Colorant Manufacture, Iran Color Research Center, P. O. Box 1665618481, Tehran, Iran.
BMC Chem. 2024 Aug 19;18(1):154. doi: 10.1186/s13065-024-01249-5.
This study investigates the solvatochromic behavior of a new D1 disperse dye, focusing on the 4-nitro-2-cyano-azo-Benzene-metaToluidine type. Using UV-visible spectroscopy, we analyze the dye's performance in single solvents and binary mixtures. Our analysis includes the evaluation of solvent polarity parameters and dye structure parameters, with emphasis on the longest wavelength intramolecular charge transfer absorption band. We identify nonlinear and linear patterns in the electronic transition energies plots with respect to solvent composition. Statistical analysis considers correlation coefficients, root mean squared error, mean absolute percentage error, and other parameters, providing insights into data accuracy and precision. This experimental and statistical study explores the absorption spectrum, wavelength characteristics, absorption energy, and polarity of a novel azo dye across various solvent and solute environments. These findings contribute to a comprehensive understanding of the dye's photophysical and photochemical properties, potentially enabling applications in optical sensors and advanced materials.
本研究调查了一种新型D1分散染料的溶剂化显色行为,重点关注4-硝基-2-氰基-偶氮苯-间甲苯胺类型。使用紫外可见光谱,我们分析了该染料在单一溶剂和二元混合物中的性能。我们的分析包括对溶剂极性参数和染料结构参数的评估,重点是最长波长的分子内电荷转移吸收带。我们确定了电子跃迁能量图中相对于溶剂组成的非线性和线性模式。统计分析考虑了相关系数、均方根误差、平均绝对百分比误差和其他参数,从而深入了解数据的准确性和精确性。这项实验和统计研究探索了一种新型偶氮染料在各种溶剂和溶质环境中的吸收光谱、波长特性、吸收能量和极性。这些发现有助于全面了解该染料的光物理和光化学性质,有望在光学传感器和先进材料中得到应用。