Adeniyi Adewale George, Emenike Ebuka Chizitere, Ezzat Abdelrahman O, Iwuozor Kingsley O, Abd-Elkader Omar H, Al-Lohedan Hamad A, Ojeyemi Toluwalase, Saka Harvis Bamidele, Emmanuel Stephen Sunday
Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, P. M. B. 1515, Nigeria.
Departments of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria.
Heliyon. 2024 Jul 31;10(15):e35485. doi: 10.1016/j.heliyon.2024.e35485. eCollection 2024 Aug 15.
Biochar production from unconventional biomass, specifically onion peel (OP) and chicken feathers (CF), was investigated in this study. Two distinct biochars were produced by doping each biomass with the other, with the aim of exploring the synergistic effects of different feedstock combinations on biochar properties. The biochar production process was conducted using a retort heating method and characterized using several techniques. A yield of 36 % was obtained for OP-doped biochar (OP92CF8-BC) and 23 % for CF-doped biochar (F92OP8-BC). Fourier Transform Infrared Spectroscopy analysis revealed characteristic functional groups from cellulose, hemicellulose, and lignin in OP92CF8-BC, while CF92OP8-BC displayed keratin-related peaks. Scanning Electron Microscopy imaging showed surface morphology differences, with OP92CF8-BC exhibiting a rougher and more porous structure compared to CF92OP8-BC. Energy-Dispersive X-ray Spectroscopy analysis confirmed the elemental composition, with OP92CF8-BC having higher carbon, calcium, and sulfur contents and CF92OP8-BC having higher nitrogen and oxygen contents. The biochar had specific surface areas of 342.4 and 200.80 m/g for OP92CF8-BC and CF92OP8-BC, respectively. According to the results, using biochar treatments-more especially, CF92OP8-BC-can significantly enhance cob weight. This could be good for agricultural productivity. These findings highlight the influence of feedstock composition on the properties of biochar and provide insights for its potential applications in soil amendment and pollutant removal.
本研究对利用非常规生物质(特别是洋葱皮(OP)和鸡毛(CF))生产生物炭进行了调查。通过将每种生物质与另一种生物质掺杂,制备了两种不同的生物炭,目的是探索不同原料组合对生物炭性质的协同效应。生物炭的生产过程采用干馏加热法,并使用多种技术对其进行表征。掺杂OP的生物炭(OP92CF8-BC)的产率为36%,掺杂CF的生物炭(F92OP8-BC)的产率为23%。傅里叶变换红外光谱分析揭示了OP92CF8-BC中纤维素、半纤维素和木质素的特征官能团,而CF92OP8-BC显示出与角蛋白相关的峰。扫描电子显微镜成像显示了表面形态的差异,与CF92OP8-BC相比,OP92CF8-BC呈现出更粗糙、更多孔的结构。能量色散X射线光谱分析证实了元素组成,OP92CF8-BC的碳、钙和硫含量较高,CF92OP8-BC的氮和氧含量较高。OP92CF8-BC和CF92OP8-BC生物炭的比表面积分别为342.4和200.80 m²/g。根据结果,使用生物炭处理——尤其是CF92OP8-BC——可以显著提高玉米穗重量。这可能有利于农业生产力。这些发现突出了原料组成对生物炭性质的影响,并为其在土壤改良和污染物去除方面的潜在应用提供了见解。