Liu Wen-Wen, Shao Xia, Teng Wei
Beijing Key Laboratory of Urban Atmospheric Volatile Organic Compounds Pollution Control and Application, National Engineering Research Center of Urban Environmental Pollution Control, Beijing Municipal Research Institute of Eco-Environmental Protection, Beijing 100037, China.
Appraisal Center for Environment and Engineering, Ministry of Ecology and Environment, Beijing 100012, China.
Huan Jing Ke Xue. 2024 Aug 8;45(8):4470-4483. doi: 10.13227/j.hjkx.202308148.
Volatile organic compounds (VOCs) from the wooden furniture-manufacturing industry are an important emission source. To study the emission characteristics of VOCs from the wooden furniture-manufacturing industry and associated environmental impacts, nine typical wooden furniture manufacturers in China were selected to carry out sample collection and VOCs detection. The maximum incremental reactivity (MIR) method and secondary organic aerosol (SOA) formation potential method were used to quantify the corresponding contributions to the generation of O and SOA. The results showed that: ① The concentrations of VOCs emitted from different types of coating exhaust gas were different. The emission concentration of VOCs in solvent-based coating exhaust gas was significantly higher than that in water-based coating exhaust gas and ultra-violet (UV) coating exhaust gas, and the VOCs emission concentrations ranged between 2.82 - 155.37, 1.13 - 104.45, and 0.57 - 1.15 mg·m, respectively. ② The main organic group in solvent-based coating exhaust gas was esters, accounting for 45.88%, and butyl acetate (31.07%) was the main VOCs species. The main organic group in water-based coating exhaust gas and UV coating exhaust gas was alcohols, and the main VOCs species in water-based coating exhaust gas and UV coating exhaust gas were both ethanol, accounting for 46.63% and 34.32%, respectively. ③ The OFP of VOCs emitted by solvent-based coating, water-based coating, and UV coating were 149.23, 50.90, and 1.87 mg·m, respectively, and the primary contributing components of OFP of different types of coating were /-xylene (26.61%), ethanol (36.35%), and ethanol (23.98%), respectively. ④ The SOA of VOCs emitted by solvent-based coating, water-based coating, and UV coating were 0.76, 0.25, and 0.01 mg·m, respectively. The SOA generation of various types of coating was dominated by aromatics(96.35%-98.96%), and the main active compounds were toluene, ethylbenzene, and xylene. ⑤ Comparing the environmental impact of exhaust gas from solvent-based coating, water-based coating, and UV coating, it was found that the OFP and SOA generated by the VOCs emitted from solvent-based coating were much higher than those for water-based coating and UV coating. Therefore, the implementation of water-based coating and UV coating substitution strategy from the source could effectively reduce VOCs emissions and abate OFP and SOA productions.
木制家具制造业产生的挥发性有机化合物(VOCs)是重要的排放源。为研究木制家具制造业VOCs的排放特征及相关环境影响,选取中国9家典型木制家具制造商进行样品采集和VOCs检测。采用最大增量反应活性(MIR)法和二次有机气溶胶(SOA)生成潜力法,量化其对臭氧(O₃)和SOA生成的相应贡献。结果表明:①不同类型涂料废气排放的VOCs浓度不同。溶剂型涂料废气中VOCs排放浓度显著高于水性涂料废气和紫外光(UV)固化涂料废气,其VOCs排放浓度分别在2.82~155.37、1.13~104.45和0.57~1.15mg·m⁻³之间。②溶剂型涂料废气中主要有机基团为酯类,占45.88%,乙酸丁酯(31.07%)为主要VOCs物种。水性涂料废气和UV固化涂料废气中主要有机基团为醇类,水性涂料废气和UV固化涂料废气中的主要VOCs物种均为乙醇,分别占46.63%和34.32%。③溶剂型涂料、水性涂料和UV固化涂料排放的VOCs的臭氧生成潜势(OFP)分别为149.23、50.90和1.87mg·m⁻³,不同类型涂料OFP的主要贡献组分分别为间/对二甲苯(26.61%)、乙醇(36.35%)和乙醇(23.98%)。④溶剂型涂料、水性涂料和UV固化涂料排放的VOCs的SOA分别为0.76、0.25和0.01mg·m⁻³。各类涂料的SOA生成以芳烃为主(96.35%~98.96%),主要活性化合物为甲苯、乙苯和二甲苯。⑤对比溶剂型涂料、水性涂料和UV固化涂料废气的环境影响,发现溶剂型涂料排放的VOCs产生的OFP和SOA远高于水性涂料和UV固化涂料。因此,从源头实施水性涂料和UV固化涂料替代策略可有效减少VOCs排放,降低OFP和SOA生成。