• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

通过C-N键形成光催化合成席夫碱:苄醇作为芳醛的可持续替代物

Photocatalyzed Synthesis of a Schiff Base via C-N Bond Formation: Benzyl Alcohol as Sustainable Surrogates of Aryl Aldehydes.

作者信息

Pandey Shikha, Singh Aman, Kushwaha Ambuj Kumar, Singh Sundaram

机构信息

Department of Chemistry, Indian Institute of Technology (BHU), Varanasi 221005,India.

出版信息

J Org Chem. 2024 Sep 6;89(17):12576-12582. doi: 10.1021/acs.joc.4c01507. Epub 2024 Aug 22.

DOI:10.1021/acs.joc.4c01507
PMID:39169829
Abstract

The advancement of photocatalytic techniques has enabled green chemical synthesis through visible-light-mediated photochemical oxidation under mild conditions. A novel approach under visible-light conditions was facilitated by eosin-Y for the reaction between substituted benzyl alcohols and anilines, resulting in the synthesis of diverse Schiff bases. This innovative method is emphasized for its environmentally friendly nature, lack of metal catalysts, cost-effectiveness, and nontoxic characteristics.

摘要

光催化技术的进步使得在温和条件下通过可见光介导的光化学氧化实现绿色化学合成成为可能。曙红Y促进了一种在可见光条件下的新方法,用于取代苄醇与苯胺之间的反应,从而合成了多种席夫碱。这种创新方法因其环境友好性、无需金属催化剂、成本效益高和无毒特性而受到重视。

相似文献

1
Photocatalyzed Synthesis of a Schiff Base via C-N Bond Formation: Benzyl Alcohol as Sustainable Surrogates of Aryl Aldehydes.通过C-N键形成光催化合成席夫碱:苄醇作为芳醛的可持续替代物
J Org Chem. 2024 Sep 6;89(17):12576-12582. doi: 10.1021/acs.joc.4c01507. Epub 2024 Aug 22.
2
One-pot synthesis of Schiff base compounds via photocatalytic reaction in the coupled system of aromatic alcohols and nitrobenzene using CdInS photocatalyst.使用 CdInS 光催化剂,在芳香醇和硝基苯的耦合体系中通过光催化反应一锅合成席夫碱化合物。
Dalton Trans. 2018 Aug 14;47(32):10915-10924. doi: 10.1039/c8dt02278j.
3
Selective photocatalytic oxidation of aromatic alcohols to aldehydes with air by magnetic WOZnO/FeO. photochemical synthesis of 2-substituted benzimidazoles.磁性WOZnO/FeO实现空气对芳香醇的选择性光催化氧化制醛。2-取代苯并咪唑的光化学合成。
RSC Adv. 2020 Nov 9;10(67):40725-40738. doi: 10.1039/d0ra08403d.
4
Unified Approach to Diverse Heterocyclic Synthesis: Organo-Photocatalyzed Carboacylation of Alkenes and Alkynes from Feedstock Aldehydes and Alcohols.多样杂环合成的统一方法:基于原料醛和醇的有机光催化烯烃和炔烃的碳酰化反应
J Org Chem. 2023 Nov 3;88(21):15374-15388. doi: 10.1021/acs.joc.3c01884. Epub 2023 Oct 23.
5
Cobalt isatin-Schiff-base derivative of MOF as a heterogeneous multifunctional bio-photocatalyst for sunlight-induced tandem air oxidation condensation process.钴靛红席夫碱 MOF 衍生物作为一种非均相多功能生物光催化剂,用于太阳光诱导串联空气氧化缩合过程。
Sci Rep. 2023 Mar 29;13(1):5115. doi: 10.1038/s41598-023-32241-z.
6
Photocatalyzed Oxidative Tandem Reaction Mediated by Bipyridinium for Multifunctional Derivatization of Alcohols.联吡啶介导的光催化氧化串联反应用于醇的多功能衍生化
ChemSusChem. 2024 Aug 12;17(15):e202301911. doi: 10.1002/cssc.202301911. Epub 2024 Apr 5.
7
New Role for Photoexcited Na Eosin Y the Direct Hydrogen Atom Transfer Process in Photochemical Visible-Light-Induced Synthesis of 2-Amino-4-Chromene Scaffolds Under Air Atmosphere.光激发的钠曙红Y在空气氛围下光化学可见光诱导合成2-氨基-4-色烯骨架中的直接氢原子转移过程的新作用
Front Chem. 2022 Jun 9;10:880257. doi: 10.3389/fchem.2022.880257. eCollection 2022.
8
Photoredox Catalysis by 21-Thiaporphyrins: A Green and Efficient Approach for C-N Borylation and C-H Arylation.21-硫杂卟啉的光氧化还原催化:一种用于C-N硼化和C-H芳基化的绿色高效方法。
Chemistry. 2024 Aug 19;30(46):e202401623. doi: 10.1002/chem.202401623. Epub 2024 Jul 16.
9
Self-Assembly of CdS/CdInS Heterostructure with Enhanced Photocascade Synthesis of Schiff Base Compounds in an Aromatic Alcohols and Nitrobenzene System with Visible Light.CdS/CdInS 异质结构的自组装在芳香醇和硝基苯体系中可见光下促进席夫碱化合物的光级联合成
ACS Appl Mater Interfaces. 2019 Dec 18;11(50):46735-46745. doi: 10.1021/acsami.9b14450. Epub 2019 Dec 6.
10
Visible Light Mediated Photoredox Catalytic Arylation Reactions.可见光介导的光氧化还原催化芳基化反应。
Acc Chem Res. 2016 Aug 16;49(8):1566-77. doi: 10.1021/acs.accounts.6b00229. Epub 2016 Aug 2.