无金属负线性压缩性（NLC）材料——1,2-双（4-吡啶基）乙烷与富马酸的共晶体。
Metal-free negative linear compressibility (NLC) material - the cocrystal of 1,2-bis(4-pyridyl)ethane and fumaric acid.
作者信息
Patyk-Kaźmierczak Ewa, Kaźmierczak Michał
机构信息
Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwerystetu Poznańskiego 8, 61-614 Poznań, Poland.
出版信息
Chem Commun (Camb). 2024 Sep 16;60(75):10310-10313. doi: 10.1039/d4cc02183e.
PMID:39169833
Abstract
Materials that show significant negative linear compressibility (NLC) reported so far suffer from a number of shortcomings that affect their applicability. The cocrystal of 1,2-bis(4-pyridyl)ethane and fumaric acid, which exhibits exceptional NLC behaviour, overcomes these problems and sets the foundation for the development of environmentally friendly metal-free NLC materials.
摘要
迄今为止报道的显示出显著负线性压缩性（NLC）的材料存在许多影响其适用性的缺点。1,2 - 双（4 - 吡啶基）乙烷与富马酸的共晶体表现出优异的NLC行为，克服了这些问题，并为开发环保型无金属NLC材料奠定了基础。
相似文献
1
Metal-free negative linear compressibility (NLC) material - the cocrystal of 1,2-bis(4-pyridyl)ethane and fumaric acid.无金属负线性压缩性（NLC）材料——1,2-双（4-吡啶基）乙烷与富马酸的共晶体。
Chem Commun (Camb). 2024 Sep 16;60(75):10310-10313. doi: 10.1039/d4cc02183e.
2
Giant Negative Compressibility by Liquid Intrusion into Superhydrophobic Flexible Nanoporous Frameworks.液体侵入超疏水柔性纳米多孔框架产生的巨大负压缩性
Nano Lett. 2021 Apr 14;21(7):2848-2853. doi: 10.1021/acs.nanolett.0c04941. Epub 2021 Mar 24.
3
Negative Linear Compressibility Due to Layer Sliding in a Layered Metal-Organic Framework.层状金属有机框架中层间滑动导致的负线性压缩性
J Phys Chem Lett. 2017 Apr 6;8(7):1436-1441. doi: 10.1021/acs.jpclett.7b00121. Epub 2017 Mar 17.
4
Giant negative linear compressibility in zinc dicyanoaurate.锌二氰合金（I）中的巨大负线性压缩系数。
Nat Mater. 2013 Mar;12(3):212-6. doi: 10.1038/nmat3551. Epub 2013 Jan 20.
5
Negative linear compressibility in nanoporous metal-organic frameworks rationalized by the empty channel structural mechanism.基于空通道结构机制对纳米多孔金属有机框架中的负线性压缩性的阐释
Phys Chem Chem Phys. 2021 Apr 14;23(14):8508-8524. doi: 10.1039/d1cp00214g. Epub 2021 Mar 25.
6
Hidden negative linear compressibility in lithium l-tartrate.左旋酒石酸锂中的隐藏负线性压缩性。
Phys Chem Chem Phys. 2017 Feb 1;19(5):3544-3549. doi: 10.1039/c6cp08690j.
7
H3O(+) tetrahedron induction in large negative linear compressibility.大负线性压缩性中H3O(+)四面体诱导
Sci Rep. 2016 May 17;6:26015. doi: 10.1038/srep26015.
8
Selected Negative Linear Compressibilities in the Metal-Organic Framework of [Cu(4,4'-bpy)(HO)]·SiF.[Cu(4,4'-联吡啶)(HO)]·SiF金属有机框架中的选定负线性压缩率
Inorg Chem. 2020 Feb 3;59(3):1715-1722. doi: 10.1021/acs.inorgchem.9b02884. Epub 2020 Jan 22.
9
Negative linear compressibility in a crystal of α-BiB3O6.α-BiB₃O₆晶体中的负线性压缩性。
Sci Rep. 2015 Aug 25;5:13432. doi: 10.1038/srep13432.
10
Large Negative Linear Compressibility in InH(BDC)₂ from Framework Hinging.框架铰链导致 InH(BDC)₂的大负线性压缩性。
J Am Chem Soc. 2017 Nov 8;139(44):15648-15651. doi: 10.1021/jacs.7b10292. Epub 2017 Oct 26.
引用本文的文献
1
Managing negative linear compressibility and thermal expansion through steric hindrance: a case study of 1,2-bis(4'-pyridyl)ethane cocrystals.通过空间位阻控制负线性压缩性和热膨胀：以1,2-双(4'-吡啶基)乙烷共晶体为例
IUCrJ. 2025 Jan 1;12(Pt 1):88-96. doi: 10.1107/S2052252524011734.
Zotero 插件