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醋酸钠添加剂对氰化物溶液浸出金的影响:实验室及半工业浸出试验

Effect of sodium acetate additive on gold leaching with cyanide solution: Laboratory and semi-pilot leaching tests.

作者信息

Surimbayev Bauyrzhan, Yessengarayev Yerlan, Khumarbekuly Yerassyl, Bolotova Lyudmila, Kanaly Yernazar, Akzharkenov Mukhitdin, Zhumabai Shyngys

机构信息

Laboratory of Precious Metals, Kazmekhanobr State Scientific Production Association of Industrial Ecology, 67 Zhandosov St, 050036, Almaty, Kazakhstan.

Department of Metallurgical Processes, Heat Engineering and Technology of Special Materials, Satbayev University, 22 Satpayev St, 050013, Almaty, Kazakhstan.

出版信息

Heliyon. 2024 Aug 6;10(15):e35805. doi: 10.1016/j.heliyon.2024.e35805. eCollection 2024 Aug 15.

Abstract

Heap leaching with a cyanide solution is used for processing low-grade ores; however, owing to the chemical, mineralogical, and physical characteristics of ores and their particle size distribution, extraction efficiencies are often low. This study investigated the effects of sodium acetate addition on gold extraction from Akshoky deposit ores under laboratory and semi-pilot laboratory test conditions. The gold-bearing ore used in this study had average gold and silver contents of 1.32 and 3.27 g/t, respectively. The chemical composition of the ore was as follows (wt%): copper: 0.0185, nickel: 0.0090, cobalt: 0.0025, zinc: 0.0470, lead: 0.0095, total iron: 4.10, calcium oxide: 3.08, magnesium oxide: 1.10, sodium oxide: 1.40, potassium oxide: 0.82, silicon oxide: 64.22, aluminum oxide: 13.37, arsenic: 0.023, antimony: 0.0024, total sulfur: 0.24, sulfate sulfur: 0.040, and sulfide sulfur: 0.20. Gold in the ore occurs in different forms: free/native form grains (82 %), covered with films (3.28 %), associated with sulfides (6.56 %), and in fine-grained form (8.20 %). Laboratory tests showed that gold dissolution from ground ore by a cyanide solution without sodium acetate addition was 83.08 %. However, with sodium acetate addition (0.1; 0.5; 1.0 kg/t), it increased to 84.38-86.61 %. Semi-pilot laboratory tests under heap-leaching conditions confirmed the positive effects of sodium acetate. The increase in gold extraction was 7.6 % (62.9 %) compared with that in the experiments without reagent addition (55.30 %).

摘要

用氰化物溶液进行堆浸用于处理低品位矿石;然而,由于矿石的化学、矿物学和物理特性及其粒度分布,提取效率往往较低。本研究在实验室和半中试实验室试验条件下,研究了添加醋酸钠对阿克肖基矿床矿石中金提取的影响。本研究中使用的含金矿石的金和银平均含量分别为1.32 g/t和3.27 g/t。矿石的化学成分如下(重量%):铜:0.0185、镍:0.0090、钴:0.0025、锌:0.0470、铅:0.0095、总铁:4.10、氧化钙:3.08、氧化镁:1.10、氧化钠:1.40、氧化钾:0.82、氧化硅:64.22、氧化铝:13.37、砷:0.023、锑:0.0024、总硫:0.24、硫酸盐硫:0.040、硫化物硫:0.20。矿石中的金以不同形式存在:游离/自然形态颗粒(82%)、被薄膜覆盖(3.28%)、与硫化物相关(6.56%)以及细粒形态(8.20%)。实验室试验表明,不添加醋酸钠时,氰化物溶液从磨碎矿石中溶解金的比例为83.08%。然而,添加醋酸钠(0.1;0.5;1.0 kg/t)后,该比例提高到84.38 - 86.61%。堆浸条件下的半中试实验室试验证实了醋酸钠的积极作用。与不添加试剂的实验(55.30%)相比,金提取率提高了7.6%(达到62.9%)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36b7/11337056/51ded026de66/gr1.jpg

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