Development of surfactant formulation for high-temperature off-shore carbonate reservoirs.

The residual oil left behind after water flooding in petroleum reservoirs can be mobilized by surfactant formulations that yield ultralow interfacial tension (IFT) with oil. However, finding ultralow IFT surfactant formulations is difficult for high-temperature, off-shore, carbonate reservoirs. These reservoirs are often water-flooded with seawater (with a lot of divalent ions), which is often incompatible with many surfactants at high temperatures. The goal of this research is to develop a surfactant formulation for an off-shore carbonate reservoir at 100°C previously flooded by seawater. Surfactant-oil-brine phase behavior was studied for formulations, starting from a single surfactant to mixtures of surfactants and a co-solvent. Mixtures of three surfactants and one co-solvent were needed to produce ultralow IFT formulations for the oil of interest. The surfactant system with polymer mobility control was tested in crushed reservoir rock packs. The cumulative oil recovery was >99% for the surfactant-polymer (SP) flood with an optimal salinity gradient. The constant salinity SP floods with seawater increased oil recovery significantly beyond the water flood (cumulative oil recovery >91%), even though the recovery was lower than that of the optimal salinity gradient SP flood. Our experimental work demonstrates the effectiveness of the surfactant formulation for a high-temperature carbonate reservoir at seawater salinity.