Cation-Induced Self-Assembly of α-MnO Nanowires into High-Purity Self-Standing Three-Dimensional Network Aerogels for Catalytic Decomposition of Carcinogenic Formaldehyde at Ambient Temperature.

Formaldehyde (HCHO), a ubiquitous gaseous pollutant in indoor environments, threatens human health under long-term exposure, necessitating its effective elimination. Due to its advantages in enhancing mass transfer and effectively exposing active sites, aerogels with a three-dimensional (3D) interconnected network structure are expected to achieve efficient and stable decomposition of HCHO at ambient temperature. However, how to realize the self-assembly of transition metal oxides to construct high-purity 3D network aerogels is still a huge challenge. Herein, the cation-induced self-assembly strategy was developed to construct high-purity self-standing 3D network manganese dioxide aerogels. The interaction between cations and the surface groups of nanowires is crucial for successful self-assembly, which leads to the cross-winding of nanowires with each other, forming a 3D-structured network. The K-induced 3D-MnO exhibited excellent catalytic performance for HCHO, which could continuously and steadily decompose HCHO into CO and HO at ambient temperature. Thanks to the 3D interconnected network structure, on the one hand, it provides a large specific surface area and porosity, reducing mass transfer resistance and promoting the adsorption of HCHO and O molecules. On the other hand, it is more important to fully expose the active sites, which can generate more surface active oxygen species and achieve effective recycling and regeneration. Importantly, 3D-MnO has a strong ability to capture and activate water molecules in the atmosphere, which could be further involved in the replenishment of the consumed hydroxyl groups. This study proposes a strategy for self-assembly of transition metal oxides through cation-induction, which provides a new catalyst design approach for the room temperature decomposition of VOCs.