Synthesis of Well-Defined Poly(vinyl alcohol--vinyl acetate) Copolymers by Alcoholysis of Poly(vinyl acetate) Synthesized by Macromolecular Design via Interchange of Xanthate Polymerization, and Their Use as a Stabilizer in Emulsion (Co)polymerization of Vinyl Acetate.

This work aims at synthesizing tailor-made poly(vinyl alcohol--vinyl acetate) (PVA) amphiphilic copolymers, obtained by alcoholysis of poly(vinyl acetate) (PVAc) that could display improved properties as stabilizers compared to commercially available PVAs. Well-defined PVAs with different alcoholysis degrees were produced from a library of PVAc homopolymers synthesized by macromolecular design via interchange of xanthate polymerization and exhibiting different degrees of polymerization degrees. Subsequently, these PVAs were evaluated as stabilizers in the emulsion copolymerization of VAc and vinyl neodecanoate (VERSA 10, referred to as V10) and compared to a commercially available reference PVA obtained by alcoholysis of PVAc formed by conventional radical polymerization. In all cases, stable latexes were obtained and compared in terms of their colloidal characteristics. To identify the best stabilizer candidate, the amount of PVA remaining in water and not participating to the particle stabilization was evaluated in each case.