Two Birds with One Stone: Impedance-Voltage Dual-Mode Low Humidity Sensor Based on LiBr-MOF-801 with High Response.

Dual-mode humidity sensors have received wide attention in recent years due to their great potential in multifunction applications. Herein, following a "two birds with one stone" strategy, a dual-mode and self-powered low humidity sensor based on LiBr-MOF-801 with high response and power generation is proposed. The optimized LiBr-MOF-801-based sensor exhibits impedance-voltage dual-mode sensitivity in the low humidity range of 0-23% relative humidity (RH) with high response (57.1 and 0.61 V), small hysteresis (0.3% RH) and good long-term stability at room temperature (20 °C). Moreover, an integrated humidity power generator is obtained by series connection of the self-powered humidity sensor within 15 cm, and the output voltage reaches 2.6 V with an output power density of 110 nW cm, and can be used as energy, supplying power to commercial electronic equipment even in low humidity. This work provides a new sight for fabricating high-performance, dual-mode, and self-powered low-humidity sensors.