基于无机-有机杂化轮烷的一维、二维和三维互锁聚合物。

One-, two- and three-dimensional interlocked polymers based on hybrid inorganic-organic rotaxanes.

作者信息

Lockyer Selena J, Whitehead George F S, Timco Grigore A, McInnes Eric J L, Winpenny Richard E P

机构信息

Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.

出版信息

Chem Commun (Camb). 2024 Sep 12;60(74):10124-10127. doi: 10.1039/d4cc03566f.

DOI:10.1039/d4cc03566f

PMID:39189716

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11348830/

Abstract

We report three new polymers, based on mechanically interlocked inorganic-organic rotaxanes. They are made in very mild conditions and involve pyrimidine head groups binding to copper(ii) linking units. A two-dimensional 6,3 net and a three-dimensional 10,3b net are found depending on the solvent used in the reaction.

摘要

我们报道了三种基于机械互锁的无机-有机轮烷的新型聚合物。它们是在非常温和的条件下制备的，并且涉及嘧啶端基与铜（II）连接单元的结合。根据反应中使用的溶剂，发现了二维的6,3网络和三维的10,3b网络。