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分叉鱼尾葵(狐尾椰树)叶片是模拟水体和废水中超强即时亚甲基蓝去除剂。

Wodyetia bifurcata (foxtail palm tree) leaves as a super-augmented instantaneous methylene blue remover from simulated water and wastewater.

机构信息

Environment Protection Laboratory, Department of Chemistry, Central University of Jharkhand, Cheri-Manatu, P.S. Kanke, Ranchi, 835222, India.

Department of Chemistry, The Graduate School College for Women Jamshedpur, Jamshedpur, 831001, India.

出版信息

Environ Monit Assess. 2024 Aug 27;196(9):848. doi: 10.1007/s10661-024-13033-y.

Abstract

Wodyetia bifurcata, also known as foxtail palm tree leaves, was tested for highly effective methylene blue (MB) removal from commercial and artificial effluent. BET surface area measurement, FESEM, FTIR, and pH were used to get information on the shape and structure of the particles. Several important factors were used to determine its adsorption activity, including intake concentration, contact duration, and pH level. Accelerated adsorption is seen in the experimental results, with more than 94% adsorption occurring successfully in the initial 12 min and reaching equilibrium within 15 min (% removal = 97.45%) at neutral pH. It was discovered that the maximum adsorption capacity was 58.74 mg g at 308 K. The adsorption procedure confirms an active adsorption process of linear and non-linear kinetics of pseudo-second order, and the adsorption path is well addressed by the Freundlich model both in linear and non-linear form, having an R value close to unity. Thermodynamic characteristics point to an exothermic, viable, spontaneous reaction with higher entropy. Utilizing a 1:1 MeOH/HO ratio, spent adsorbent may be readily regenerated by as much as 75% with a possible three-cycle usage. The practical application of biosorbents was confirmed by real-time effectiveness testing using MB-carrying industrial wastewater, and up to 45.75% adsorption was shown. A relative standard deviation confirmed statistical dependability. All things considered, the current material provides a clean and environmentally friendly way to remove MB dye from various wastewater types.

摘要

分叉鱼尾葵,又称狐尾椰树叶,经测试可有效去除商业和人工废水中的亚甲基蓝(MB)。BET 表面积测量、FESEM、FTIR 和 pH 值用于获取有关颗粒形状和结构的信息。使用了几个重要因素来确定其吸附活性,包括摄入浓度、接触时间和 pH 值。实验结果表明,吸附过程迅速,在最初的 12 分钟内成功吸附了超过 94%的亚甲基蓝,在中性 pH 值下 15 分钟内达到平衡(去除率=97.45%)。研究发现,最大吸附容量为 308 K 时为 58.74mg/g。吸附过程证实了线性和非线性拟二级动力学的主动吸附过程,吸附路径在线性和非线性形式下均由 Freundlich 模型很好地解决,R 值接近 1。热力学特性表明这是一个放热、可行、自发的反应,熵值较高。利用 1:1 的 MeOH/HO 比例,用过的吸附剂可在 75%左右轻松再生,可能进行三周期使用。通过实时测试含 MB 的工业废水的实际应用,证实了生物吸附剂的实际应用,显示出高达 45.75%的吸附效果。相对标准偏差证实了统计可靠性。总的来说,这种材料提供了一种从各种废水类型中去除 MB 染料的清洁环保方法。

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