Environment Protection Laboratory, Department of Chemistry, Central University of Jharkhand, Cheri-Manatu, P.S. Kanke, Ranchi, 835222, India.
Department of Physics, Government Polytechnic College, Jhunjhunu, 333001, Rajasthan, India.
Environ Monit Assess. 2024 Jul 13;196(8):728. doi: 10.1007/s10661-024-12866-x.
This study investigates the potential of using Ficus religiosa inflorescence (peepal tree) as an efficient solution for removing crystal violet from simulated and industrial wastewater. Various analyses were conducted to understand the adsorbent's structure, including particle morphology, BET surface area, FTIR, and pH. The adsorption process was studied under different physicochemical factors such as temperature, concentration, contact time, and pH. Results revealed rapid adsorption, with 94.15% removal efficiency within the first 15 min at neutral pH. The highest observed adsorption capacity was 198.03 mg g, following pseudo-second-order kinetics (R = 0.99), indicating chemisorption. The Langmuir model accurately described the adsorption pathway (R = 0.99), showing monolayer adsorption. Thermodynamic analysis indicated an exothermic, feasible, and spontaneous process with increased entropy. The adsorbent could be easily regenerated using a 1:1 MeOH/HO mixture for up to three cycles, yielding up to 73.86%. Real-time application with industrial effluent containing crystal violet showed up to 44.70% adsorption. The experiments demonstrated reliability with evaluated standard deviations (0.017935-0.000577) and relative standard deviations (0.439-0.673%), confirming statistical reliability. In conclusion, it presents a sustainable and eco-friendly approach for removing crystal violet dye from diverse wastewater sources.
本研究探讨了利用菩提树花序(菩提榕)作为有效去除模拟和工业废水中结晶紫的方法。进行了各种分析来了解吸附剂的结构,包括颗粒形态、BET 表面积、FTIR 和 pH。研究了不同物理化学因素(如温度、浓度、接触时间和 pH)下的吸附过程。结果表明,在中性 pH 下,前 15 分钟内吸附速率很快,去除效率达到 94.15%。观察到的最高吸附容量为 198.03mg/g,遵循准二级动力学(R=0.99),表明为化学吸附。Langmuir 模型准确描述了吸附途径(R=0.99),表明为单层吸附。热力学分析表明,该过程是放热、可行和自发的,熵增加。吸附剂可以使用 1:1 的 MeOH/HO 混合物轻松再生,最多可进行三个循环,产率高达 73.86%。在含有结晶紫的工业废水中的实时应用表明,吸附率高达 44.70%。实验结果通过评估标准偏差(0.017935-0.000577)和相对标准偏差(0.439-0.673%)得到验证,表明统计可靠性。综上所述,该研究为从各种废水源中去除结晶紫染料提供了一种可持续和环保的方法。