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研究等离子体电解氧化和湿后处理对 AA7075 表面的协同影响。

Study of the Synergistic Influence of Plasma Electrolytic Oxidation and Wet Post-Treatment on the Surface of AA7075.

机构信息

King Abdulaziz City for Science and Technology (KACST), Riyadh 12354, Saudi Arabia.

Tamaheer Program, Saudi Human Resources Development Fund, Riyadh 12213, Saudi Arabia.

出版信息

ACS Appl Bio Mater. 2024 Sep 16;7(9):5965-5976. doi: 10.1021/acsabm.4c00528. Epub 2024 Aug 28.

DOI:10.1021/acsabm.4c00528
PMID:39194162
Abstract

In this study, we enhanced the corrosion and microbial resistance of aluminum 7075 alloys by applying a thin layer of alumina through plasma electrolytic oxidation (PEO) in an alkali-silicate electrolyte. In addition, the influence of film sealing on coated aluminum alloy 7075 was studied in detail, specifically in oil and water at 100 °C after treatment. The surface and cross-sectional morphology, element composition, and phase composition of the PEO coatings were characterized by using scanning electron microscopy (SEM) assisted with energy-dispersive X-ray spectrometry (EDS) and X-ray diffraction (XRD), respectively. The corrosion resistance of the coating on AA7075 PEO was evaluated before and after post-treatment using hot water and hump oil at 100 °C. This assessment was conducted by using various electrochemical techniques, including open-circuit potential (OCP), linear polarization resistance (LPR), potentiodynamic polarization scan (PD), electrochemical impedance spectroscopy (EIS), and cyclic potentiodynamic scan (CPS). The results showed that the corrosion resistance of the AA7075 alloy was significantly improved after the PEO coating. The AA7075 + SF, among all of the examined alloys, exhibited superior corrosion properties, due to its fat sealing. This is probably due to the formation of a mixed fatty acid layer from oil on the surface of the AA7075 PEO, which synthesizes a hydrophobic layer. Interestingly, the samples treated with PEO showed a great resistance to microbial growth.

摘要

在这项研究中,我们通过在堿性硅酸钠电解液中进行等离子体电解氧化(PEO),在铝 7075 合金上施加一层氧化铝薄层,从而提高了其耐腐蚀性和耐微生物性。此外,我们还详细研究了涂层铝合金 7075 的封孔处理对其的影响,特别是在 100°C 的油和水中进行处理后的影响。我们使用扫描电子显微镜(SEM)和能量色散 X 射线光谱仪(EDS)以及 X 射线衍射仪(XRD)分别对 PEO 涂层的表面和横截面形貌、元素组成和相组成进行了表征。我们使用各种电化学技术,包括开路电位(OCP)、线性极化电阻(LPR)、动电位极化扫描(PD)、电化学阻抗谱(EIS)和循环动电位扫描(CPS),评估了 PEO 涂层处理前后在 100°C 的热水和粘稠油中的耐腐蚀性。结果表明,PEO 涂层显著提高了 AA7075 合金的耐腐蚀性。在所有被研究的合金中,AA7075 + SF 的耐腐蚀性最好,这是因为其具有脂肪封孔处理。这可能是由于在 AA7075 PEO 的表面上形成了一层混合脂肪酸层,从而合成了一层疏油层。有趣的是,经过 PEO 处理的样品显示出对微生物生长的很强抵抗力。

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