Fardoun Hassan, Ascensão Guilherme, Mantas Pedro, Ferreira Victor
Builders Ecole d'Ingénieurs, COMUE Normandie Université, 1 Rue Pierre et Marie Curie, 14610 Epron, France.
RISCO, Department of Civil Engineering, University of Aveiro, 3810-193 Aveiro, Portugal.
Materials (Basel). 2024 Aug 12;17(16):4002. doi: 10.3390/ma17164002.
Thermoactivated recycled cement (RC) is a growing area of research and development in the cement industry. The approach represents a reversible process of cement hydration in which dehydrated compounds with similar characteristics to cement are obtained by means of thermal activation. To avoid CO emissions during the production of such RC, this study assesses the possibility of replacing ordinary Portland cement (OPC) with hardened cement powder (HCP) prepared with different proportions of hydrated lime (HL), relying on a second pozzolanic reaction, and compares it with RC mortars. Due to the thermal activation of HCP, the compressive strength increases by 11.5%. The addition of 8% HL produced an important increase in strength from 28 days to 90 days by 12.8%, although without surpassing the strength values of mortar produced only with HCP or with RC. The compressive strength results suggest the existence of a secondary pozzolanic reaction when using HCP from a cement paste source, but such a pozzolanic reaction was fully perceived in XRD patterns when using concrete as parent material, unlike cement paste, possibly due to large crystalline sand peaks that could have hindered the effective identification of smaller crystalline peaks.
热活化再生水泥(RC)是水泥行业中一个不断发展的研发领域。该方法代表了水泥水化的一个可逆过程,其中通过热活化获得具有与水泥相似特性的脱水化合物。为了避免在这种RC生产过程中产生二氧化碳排放,本研究评估了用不同比例熟石灰(HL)制备的硬化水泥粉末(HCP)替代普通硅酸盐水泥(OPC)的可能性,这依赖于二次火山灰反应,并将其与RC砂浆进行比较。由于HCP的热活化,抗压强度提高了11.5%。添加8%的HL使强度从28天到90天有了12.8%的显著提高,尽管未超过仅用HCP或RC生产的砂浆的强度值。抗压强度结果表明,当使用来自水泥浆体源的HCP时存在二次火山灰反应,但与水泥浆体不同,当使用混凝土作为母体材料时,这种火山灰反应在XRD图谱中能被充分观察到,这可能是由于大的结晶砂峰阻碍了对较小结晶峰的有效识别。