Tang Wei, Xing Guansheng, Xu Xiuwen, Chen Bing
College of Electronic and Optical Engineering and College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
School of Chemistry and Life Sciences, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
Sensors (Basel). 2024 Aug 14;24(16):5258. doi: 10.3390/s24165258.
Glassy hybrid metal halides have emerged as promising materials in recent years due to their high structural adjustability and low melting points, offering unique merits that overcome the limitations of their crystalline and polycrystalline counterparts as well as other conventional amorphous semiconductors. This review article comprehensively explores the structural characteristics, electronic properties, and chemical coordination of hybrid metal halides, emphasizing their role in the glass transition from the crystalline phase to the amorphous phase. We examine the intrinsic disorder within the amorphous phase that facilitates light transmission and discuss recent advances in device architecture and interface engineering by optimizing the charge transport of glassy hybrid metal halides for high-quality applications. With full theoretical understanding and rational structural design, potential applications in displays, information storage, X-ray imaging, and sensing are highlighted, underscoring the transformative impact of glassy hybrid metal halides in the fields of materials science and information science.
近年来，玻璃态混合金属卤化物因其高结构可调性和低熔点而成为有前景的材料，具有独特的优点，克服了其晶体和多晶同类材料以及其他传统非晶半导体的局限性。这篇综述文章全面探讨了混合金属卤化物的结构特征、电子性质和化学配位，强调了它们在从晶相到非晶相的玻璃转变中的作用。我们研究了促进光传输的非晶相内的固有无序，并讨论了通过优化玻璃态混合金属卤化物的电荷传输以实现高质量应用的器件结构和界面工程的最新进展。通过充分的理论理解和合理的结构设计，突出了在显示、信息存储、X射线成像和传感方面的潜在应用，强调了玻璃态混合金属卤化物在材料科学和信息科学领域的变革性影响。
