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柔性钙钛矿太阳能电池:为太阳能电池技术提供动力的未来物联网,简短综述。

Flexible Perovskite Solar Cells: A Futuristic IoTs Powering Solar Cell Technology, Short Review.

作者信息

Tiwari Jai Prakash

机构信息

Advanced Materials and Devices Metrology Division, CSIR-National Physical Laboratory, K.S. Krishnan Marg, Pusa Road, New Delhi, 110012, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India.

出版信息

Small Methods. 2025 Jan;9(1):e2400624. doi: 10.1002/smtd.202400624. Epub 2024 Aug 29.

Abstract

The perovskite solar cells (PSCs) technology translated on flexible substrates is in high demand as an alternative powering solution to the Internet of Things (IOTs). An efficiency of ∼26.1% on rigid and ∼25.09% on flexible substrates has been achieved for the PSCs. Further, it is also reported that F-PSC modules have a surface area of ∼900 cm, with a PCE of ∼16.43%. This performance is a world record for an F-PSC device more significant than ∼100 cm. The process optimization, and use of new transport materials, interface, and compositional engineering, as well as passivation, have helped in achieving such kind of performance of F-PSCs. Hence, the review focuses mainly on the progress of F-PSCs and the low-temperature fabrication methods for perovskite films concerning their full coverage, morphological uniformity, and better crystallinity. The transmittance, band gap matching, carrier mobility, and ease of low-temperature processing are the key figures of merit of interface layers. Electrode material's flexible and transparent nature has enhanced the device's mechanical stability. Stability, flexibility, and scalable F-PSC fabrication challenges are also addressed. Finally, an outlook on F-PSC applications for their commercialization based on cost will also be discussed in detail.

摘要

作为物联网(IOT)的一种替代供电解决方案,在柔性基板上制备的钙钛矿太阳能电池(PSC)技术需求旺盛。刚性基板上的PSC效率达到了约26.1%,柔性基板上达到了约25.09%。此外,据报道,F-PSC模块的表面积约为900平方厘米,功率转换效率(PCE)约为16.43%。这一性能是面积大于约100平方厘米的F-PSC器件的世界纪录。工艺优化、新型传输材料的使用、界面和成分工程以及钝化处理有助于实现F-PSC的这种性能。因此,本综述主要关注F-PSC的进展以及钙钛矿薄膜的低温制备方法,涉及它们的全覆盖、形态均匀性和更好的结晶度。界面层的关键性能指标包括透光率、带隙匹配、载流子迁移率以及低温加工的难易程度。电极材料的柔性和透明特性增强了器件的机械稳定性。还讨论了稳定性、柔性以及可扩展的F-PSC制造面临的挑战。最后,还将详细讨论基于成本的F-PSC商业化应用前景。

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