Wu Zipeng, Zhang Xudong, Chen Lina, Lou Qi, Zong Dehua, Deng Kelun, Cheng Zhaofang, Xia Minggang
Department of Applied Physics, School of Physics, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China.
MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China.
ACS Sens. 2024 Sep 27;9(9):4721-4730. doi: 10.1021/acssensors.4c01111. Epub 2024 Aug 30.
The continuous and stable monitoring by sensors is crucial for ensuring the safe utilization of hydrogen due to its inherent high explosiveness. Currently, catalyst aging and oxygen dependence often limit the lifetime of most sensors, which stems from the sensing materials and catalytic reaction in comparison to thermal conductivity sensors. Thermal conductivity sensors possess superior sensing characteristics such as lowpower consumption and exceptional stability attributed to their free-catalysts or free-oxygen nature. Herein, we present an ultralow-power hydrogen-thermal conductivity sensor based on suspended bare platinum nanowires. This sensor incorporates two suspended independent working elements (serpentine/bridge), each of which is thermally decoupled from the substrate. Also, the bridge element operates at significantly lower power levels (the lowest ∼3.32 μW) compared to existing direct-current hydrogen-thermal conductivity sensors. Furthermore, it demonstrates a 99.99% linearity between hydrogen concentration and response under various operating powers. Finally, our sensor shows remarkable stability through a repeatability test (>30,000 cycles). This developed platform provides an optimal structure scheme for integrated sensors with ultralow-power, extremely stable, highly linear-response sensing characteristics, which is expected to be widely used for hydrogen detection and leakage warning under various pipeline distribution systems.
由于氢气固有的高爆炸性,通过传感器进行连续稳定的监测对于确保氢气的安全使用至关重要。目前,催化剂老化和对氧气的依赖性常常限制了大多数传感器的使用寿命,这源于传感材料和催化反应,与热导率传感器相比情况如此。热导率传感器具有卓越的传感特性,如低功耗和出色的稳定性,这归因于其无催化剂或无氧气的性质。在此,我们展示了一种基于悬浮裸铂纳米线的超低功耗氢热导率传感器。该传感器包含两个悬浮的独立工作元件(蛇形/桥形),每个元件都与基板热解耦。此外,与现有的直流氢热导率传感器相比,桥形元件的工作功率水平显著更低(最低约3.32 μW)。此外,在各种工作功率下,它在氢气浓度与响应之间呈现出99.99%的线性关系。最后,通过重复性测试(>30,000次循环),我们的传感器显示出卓越的稳定性。这个开发的平台为具有超低功耗、极其稳定、高线性响应传感特性的集成传感器提供了一种优化的结构方案,有望广泛应用于各种管道输送系统下的氢气检测和泄漏预警。