Laboratório Associado para a Química Verde - REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto, Portugal.
REQUIMTE/LAQV, Instituto Superior de Engenharia do Porto, Instituto Politécnico do Porto, Porto, Portugal, Rua Dr. António Bernardino de Almeida, 431, 4249-015 Porto, Portugal.
Food Chem. 2024 Dec 15;461:140945. doi: 10.1016/j.foodchem.2024.140945. Epub 2024 Aug 20.
This work explores the potential of anthocyanin-based extracts (hibiscus calyxes - HC, red cabbage - RC, and butterfly pea flower - BPF) as natural alternatives to synthetic dyes in the food industry. Analyses in a pH range for food applications revealed higher color stability for the BPF extract, keeping vibrant colors over the 7 days at room temperature. At pH 3 and 100 °C, the BPF was more stable, losing half of its anthocyanin concentration after 14 h, while RC and HC lost half of their color after 7 and 2 h, respectively. The bisulfite bleaching followed a second-order reaction for HC and RC, and a first-order reaction for BPF, suggesting a minor effect of the bisulfite on this extract. Incorporating these extracts into porcine protein and agar-agar gelatin formulations produced consistent products with appealing hues, particularly the blue and purple colors for BPF and RC, dependent on the pH.
本研究探索了花色苷基提取物(玫瑰茄花萼 - HC、红甘蓝 - RC 和蝶豆花 - BPF)作为食品工业中合成染料的天然替代品的潜力。在食品应用的 pH 值范围内进行分析,结果表明 BPF 提取物具有更高的颜色稳定性,在室温下 7 天内保持鲜艳的颜色。在 pH 3 和 100°C 下,BPF 更稳定,在 14 小时后仅损失一半的花青素浓度,而 RC 和 HC 分别在 7 和 2 小时后失去一半的颜色。亚硫酸氢盐漂白反应遵循 HC 和 RC 的二级反应,以及 BPF 的一级反应,表明亚硫酸氢盐对该提取物的影响较小。将这些提取物加入猪蛋白和琼脂明胶配方中,可得到具有吸引力色调的一致产品,特别是 BPF 和 RC 的蓝色和紫色,这取决于 pH 值。