Lu Junchi
College of Mechanical and Vehicle Engineering, Chongqing University, Chongqing 400044, China.
ACS Omega. 2024 Aug 15;9(34):36825-36834. doi: 10.1021/acsomega.4c06023. eCollection 2024 Aug 27.
To solve the problem of poor stability and low enhanced oil recovery efficiency of conventional foam, nanoparticle-surfactant-stabilized nitrogen foam was prepared, and the influence of temperature, salinity, oil content, and pressure on foam performance was systematically investigated. Then, the flow behavior of conventional foam and nanoparticle-surfactant-stabilized foam in porous media was studied. Parallel sand pack flooding and visualization microflooding experiments were performed to investigate the enhanced oil recovery ability of nanoparticle-surfactant-stabilized foam from core-scale to pore-scale. Results showed that the nanoparticles can improve foam performance. When the temperature increases from 60 to 100 °C, the foam volume and foam half-life of nanoparticle-surfactant-stabilized foam decrease by 20 and 36%, respectively. The nanoparticle-surfactant-stabilized foam has a good salt resistance. The oil content limit value of the foam performance is 15%. With the increase of pressure, the foaming performance and foam stability are enhanced obviously. Compared with conventional surfactant-stabilized foam, the nanoparticle-surfactant-stabilized foam can have better plugging and expansion of the swept volume capacity. The micromodel flooding results are consistent with the parallel sand pack flooding results. Compared with conventional surfactant stabilized foam, nanoparticle-surfactant-stabilized foam has better enhanced oil recovery ability than conventional surfactant-stabilized foam due to its higher foaming ability, foam stability, and sweep efficiency improvement ability.
为解决常规泡沫稳定性差和提高采收率效率低的问题,制备了纳米颗粒-表面活性剂稳定的氮气泡沫,并系统研究了温度、盐度、含油率和压力对泡沫性能的影响。然后,研究了常规泡沫和纳米颗粒-表面活性剂稳定泡沫在多孔介质中的流动行为。进行了平行砂充填驱替和可视化微驱替实验,以研究纳米颗粒-表面活性剂稳定泡沫从岩心尺度到孔隙尺度的提高采收率能力。结果表明,纳米颗粒可以改善泡沫性能。当温度从60℃升高到100℃时,纳米颗粒-表面活性剂稳定泡沫的泡沫体积和泡沫半衰期分别降低了20%和36%。纳米颗粒-表面活性剂稳定泡沫具有良好的耐盐性。泡沫性能的含油率极限值为15%。随着压力的增加,发泡性能和泡沫稳定性明显增强。与常规表面活性剂稳定泡沫相比,纳米颗粒-表面活性剂稳定泡沫对波及体积的封堵和扩展能力更好。微观模型驱替结果与平行砂充填驱替结果一致。与常规表面活性剂稳定泡沫相比,纳米颗粒-表面活性剂稳定泡沫具有更高的发泡能力、泡沫稳定性和提高波及效率的能力,因此其提高采收率的能力优于常规表面活性剂稳定泡沫。