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评估北极圈内新地岛土壤样本中的有毒元素和放射性核素。

Evaluation of the potentially toxic elements and radionuclides in the soil sample of Novaya Zemlya in the Arctic Circle.

机构信息

Joint Institute for Nuclear Research, Joliot-Curie 6, 141980, Dubna, Russia.

Joint Institute for Nuclear Research, Joliot-Curie 6, 141980, Dubna, Russia.

出版信息

Environ Pollut. 2024 Nov 15;361:124871. doi: 10.1016/j.envpol.2024.124871. Epub 2024 Aug 31.

DOI:10.1016/j.envpol.2024.124871
PMID:39222768
Abstract

The study presented here elucidate the concentrations of radionuclides and potentially toxic elements in the soil samples around the Novaya Zemlya in the Russian Arctic zone, determined using HPGe gamma spectrometry, inductively coupled plasma optical emission spectrometry and direct mercury analyzer. The average detected concentrations for Ra, Th, K, U and Cs were 36.40, 46.06, 768, 2.06 and 4.71 Bq/kg, respectively. At many sampling sites, the concentrations of potentially toxic elements (Zn, Cu, Pb, Cd, Ni, and Cr) were higher than the natural levels. Positive Matrix Factorization analysis revealed the contribution of oil dumps (32%), natural sources (16%), bird colonies (32%) and atmospheric deposition (20%) for elevated elements content. In the case of radionuclides, the natural occurring contamination (38%) was primary source followed by dumped material (32%) and bird colonies (30%). The radiological risk from radionuclides was relatively high, yet still under permissible levels. For potentially toxic elements, Fe was predominant non-carcinogenic pollutant and Ni emerged as major carcinogenic contaminant. Keeping in view the high content of some elements, future studies are required to keep the human and ecological risk low, and to establish scientific grounds for the contribution of settled bird species. The findings of the study advance the present knowledge about the contamination of the study area and lays the path for further effort.

摘要

本研究阐明了俄罗斯北极地区新地岛上土壤样本中放射性核素和潜在有毒元素的浓度,使用 HPGe 伽马谱仪、电感耦合等离子体发射光谱法和直接汞分析仪进行了测定。Ra、Th、K、U 和 Cs 的平均检测浓度分别为 36.40、46.06、768、2.06 和 4.71 Bq/kg。在许多采样点,潜在有毒元素(Zn、Cu、Pb、Cd、Ni 和 Cr)的浓度高于自然水平。正矩阵因子分析揭示了油渣(32%)、自然源(16%)、鸟类聚居地(32%)和大气沉降(20%)对高浓度元素的贡献。就放射性核素而言,自然发生的污染(38%)是主要来源,其次是倾倒物(32%)和鸟类聚居地(30%)。放射性核素的放射性风险相对较高,但仍在允许水平内。对于潜在有毒元素,Fe 是主要的非致癌污染物,而 Ni 则是主要的致癌污染物。鉴于某些元素含量较高,未来的研究需要降低人类和生态风险,并为定居鸟类的贡献提供科学依据。本研究的结果增进了对研究区域污染状况的认识,并为进一步研究奠定了基础。

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