Advanced Engineering Materials and Composites Research Centre (AEMC), Department of Mechanical and Manufacturing Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia.
Advanced Engineering Materials and Composites Research Centre (AEMC), Department of Mechanical and Manufacturing Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia; Institute of Energy Infrastructure (IEI), Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Malaysia.
Int J Biol Macromol. 2024 Oct;278(Pt 3):134421. doi: 10.1016/j.ijbiomac.2024.134421. Epub 2024 Sep 2.
In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanocomposites utilizing solution blending process with acetone as the solvent with the different CNF loadings (0.1, 0.25, and 0.5 wt%). An ultrasonic bath was used in conjunction with mechanical stirring to guarantee that CNF was effectively dispersed throughout the green epoxy. The resultant nanocomposites underwent thorough evaluation, comparing them to unfilled green epoxy and evaluating their morphological, mechanical, and thermal behavior using a variety of instruments. Field-emission scanning electron microscopy (FE-SEM) was used to validate findings, which showed that the CNF were dispersed optimally inside the nanocomposites. The thermal degradation temperature (Td) of the nanocomposites showed a marginal decrement of 0.8 % in temperatures (from 348 °C to 345 °C), between unfilled green epoxy (neat) and 0.1 wt% of CNF loading. The mechanical test results, which showed a 13.3 % improvement in hardness and a 6.45 % rise in tensile strength when compared to unfilled green epoxy, were in line with previously published research. Overall, the outcomes showed that green nanocomposites have significantly improved in performance.
在这项研究中,通过将油棕纤维素纳米纤维(CNF)作为纳米填充物有效地纳入到具有 28%碳含量的生物量制成的绿色聚合物基质中,力学性能得到了显著提高。研究的目的是利用溶液共混工艺,以丙酮作为溶剂,制备绿色环氧纳米复合材料,其中 CNF 的负载量分别为 0.1%、0.25%和 0.5%(wt%)。采用超声浴和机械搅拌相结合的方法,确保 CNF 能够有效地分散在绿色环氧基体中。对得到的纳米复合材料进行了全面的评估,将其与未填充的绿色环氧进行了比较,并使用各种仪器对其形态、力学和热性能进行了评估。场发射扫描电子显微镜(FE-SEM)用于验证研究结果,结果表明 CNF 能够在纳米复合材料中得到最佳分散。纳米复合材料的热降解温度(Td)显示,与未填充的绿色环氧(纯)相比,在 0.1wt%的 CNF 负载量下,纳米复合材料的温度略有下降,降幅为 0.8%(从 348°C 降至 345°C)。与未填充的绿色环氧相比,力学测试结果显示硬度提高了 13.3%,拉伸强度提高了 6.45%,这与之前发表的研究结果一致。总的来说,研究结果表明绿色纳米复合材料的性能得到了显著提高。