Li Qianqian, Ji Keju, Zhao Jiahui, Zou Peng, Wang Xipeng, Chen Jian, Li Conghui, Li Zhili, Deng Kai, Ji Yuanming, Li Yinghui, Dai Zhendong
College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
National Key Laboratory of Space Medicine, China Astronaut Research and Training Center, Beijing 100094, China.
ACS Appl Mater Interfaces. 2024 Sep 18;16(37):49985-49992. doi: 10.1021/acsami.4c11410. Epub 2024 Sep 4.
The organisms of animals with full spatial motion ability present fine and complex 3D structures, showing reliable adhesion ability to the substrate. As core issues, the design and manufacture of complex morphology are essential in bionic adhesion technology. Specifically, the end-expanded microstructure array of high adhesion under low preload has widespread potential in the nondestructive fixation and handling of fragile objects. In the fabrication of end-expanded microstructures, the design and manufacture of metal molds with good mechanical strength are the key. In this paper, a microfabrication technology for manufacturing nickel molds based on three-dimensional printing and electroplating was proposed. The effect of the electric field inhomogeneity on the electrodeposition morphology was systematically studied. Typical bionic adhesives with expanded ends were obtained by a roll-to-roll hot embossing (R2R-HE) process. The normal adhesion force of the bionic adhesives is 9.5 N/cm, which is comparable to that of the gecko. The electroplating process assisted by 3D printing provides a new approach for the fabrication of complex bionic morphologies and large-area bionic adhesion structures.
具有完全空间运动能力的动物机体呈现出精细而复杂的三维结构,对基底表现出可靠的附着能力。作为核心问题,复杂形态的设计与制造在仿生附着技术中至关重要。具体而言,低预载下高附着力的端部扩展微结构阵列在易碎物体的无损固定和处理方面具有广泛的潜力。在端部扩展微结构的制造中,具有良好机械强度的金属模具的设计与制造是关键。本文提出了一种基于三维打印和电镀制造镍模具的微制造技术。系统研究了电场不均匀性对电沉积形态的影响。通过卷对卷热压印(R2R-HE)工艺获得了典型的端部扩展仿生粘合剂。仿生粘合剂的法向附着力为9.5 N/cm²,与壁虎的相当。三维打印辅助的电镀工艺为复杂仿生形态和大面积仿生附着结构的制造提供了一种新方法。