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Selective colorimetric sensing of histidine in aqueous media via Ag nanotriangles in the presence of HgCl.

作者信息

Namazi Koochak Niloofar, Fatmehsari Haghshenas Davoud, Firoozi Sadegh, Hassanzadeh Mohammadreza

机构信息

Department of Materials and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran, Iran.

Department of Materials and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran, Iran.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2025 Jan 15;325:125072. doi: 10.1016/j.saa.2024.125072. Epub 2024 Aug 31.

DOI:10.1016/j.saa.2024.125072
PMID:39232307
Abstract

Silver nanotriangles (AgNTs) were successfully synthesized as a colorimetric probe for selective and sensitive histidine detection in aqueous media within a 15-100 µM range and a detection limit of 330 nM using UV-Vis spectroscopy. The interaction of HgCl with AgNTs would lead to the formation of disk-shaped Ag/Hg amalgam as observed from the transmission electron images and X-ray diffraction patterns. Histidine prevents these structural and morphological changes and accordingly, the detection approach was developed based on the correlation between the histidine concentration and the in-plane dipole plasmon resonance (DPR) intensity.

摘要

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