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均苯四甲酸酐-3,4,9,10-苝四羧酸二酰亚胺二酯的合成、表征及其在聚酯纤维、聚苯乙烯和聚甲基丙烯酸甲酯薄膜染色中的应用。

Diesters of monoimide of perylene-3,4,9,10-tetracarboxylic acid - Synthesis, characterization, and application for dyeing polyester fibre, polystyrene, and poly (methyl methacrylate) films.

机构信息

Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego 16, Lodz, Poland.

Lukasiewicz Research Network, Lodz Institute of Technology, Zgierska 73, Lodz, Poland.

出版信息

Luminescence. 2024 Sep;39(9):e4890. doi: 10.1002/bio.4890.

Abstract

Three dyes-diesters of monoimides of perylene-3,4,9,10-tetracarboxylic acid were synthesized in three-stage process: esterification, hydrolysis, and monoimidation as potential fluorescent light-stable colorants for high visibility safety wear. The structure of these compounds was confirmed by H nuclear magnetic resonance spectroscopy and mass spectrometry, and their spectroscopic and physicochemical properties were determined. Colorants were applied to dyeing polyester fibre and polystyrene and poly (methyl methacrylate) films. The light, wash, and rubbing fastness of the dyeings were determined, and chromaticity coordinates were measured and discussed.

摘要

三种染料-均苯三甲酰亚胺的单酰亚胺的对苯二甲酸-3,4,9,10-四羧酸被合成在三个阶段的过程:酯化,水解,和单酰亚胺作为潜在的荧光稳定的着色剂,用于高可见性安全服。这些化合物的结构通过 H 核磁共振光谱和质谱法得到证实,并确定了它们的光谱和物理化学性质。着色剂被应用于聚酯纤维和聚苯乙烯以及聚甲基丙烯酸甲酯薄膜的染色。测定了染色的耐光,耐洗和耐摩擦牢度,并测量和讨论了色度坐标。

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