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探索废弃蛋壳的化学性质及其多样化的应用。

Exploring the chemistry of waste eggshells and its diverse applications.

机构信息

Department of Chemistry Allama, Iqbal Open University, Islamabad 44000, Pakistan.

Department of Chemistry Allama, Iqbal Open University, Islamabad 44000, Pakistan.

出版信息

Waste Manag. 2024 Dec 1;189:348-363. doi: 10.1016/j.wasman.2024.08.024. Epub 2024 Sep 4.

DOI:10.1016/j.wasman.2024.08.024
PMID:39236470
Abstract

The large-scale production of chicken eggs results in a substantial amount of eggshell (ES) residue, often considered as waste. These discarded shells naturally decompose in soil approximately within a year. Eggshells (ES), comparatively contribute lesser towards environmental pollution, contain a remarkable amount of calcium, which can be converted into various valuable products that finds applications in industries, pharmaceuticals, and medicine. Among the diverse applications of ES, most effective and promising applications are removal of heavy metals (Cd, Cr, Pb, Zn, and Cu) ∼93-99 % metal adsorption capacity and capturing of flue gases (CO and SO) from the environment. With ES having a maximum CO sorption capacity of 92 % as compared to other sources, and SO adsorption capacity of Calcined ES∼11.68 mg/g. The abundance, low cost and easy availability of CaO from ES makes them sustainable and eco-friendly. Additionally, its versatility extends beyond environmental prospects, as it is widely used in various industries as a catalyst, sorbent, fertilizer, and calcium supplement in food for individuals, plants and animals, among other diverse fields of study. Owing to its versatile applications, current review focuses on structure, chemical composition, treatment methods, and valorization pathways for diverse applications, aiming to reduce the eggshells waste and mitigate environmental pollution.

摘要

鸡蛋的大规模生产会产生大量的蛋壳(ES)残余物,通常被视为废物。这些废弃的蛋壳会在土壤中自然分解,大约需要一年的时间。蛋壳(ES)相对来说对环境污染的贡献较小,含有大量的钙,可以转化为各种有价值的产品,应用于工业、制药和医学领域。在 ES 的众多应用中,去除重金属(Cd、Cr、Pb、Zn 和 Cu)93-99%的金属吸附能力和从环境中捕获烟道气(CO 和 SO)是最有效和最有前途的应用。与其他来源相比,ES 的最大 CO 吸附能力为 92%,煅烧后的 ES 的 SO 吸附能力为11.68mg/g。ES 中 CaO 的丰富、低成本和易得性使它们具有可持续性和环保性。此外,它的多功能性不仅限于环境前景,还广泛应用于各个行业,作为催化剂、吸附剂、肥料和食品中的钙补充剂,用于个人、植物和动物等各种研究领域。鉴于其广泛的应用,本综述重点介绍了蛋壳的结构、化学成分、处理方法和多样化的应用途径,旨在减少蛋壳废物和减轻环境污染。

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Nanoscale Adv. 2025 Apr 30. doi: 10.1039/d5na00400d.