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从自然界中寻找阻断眼损伤的材料:姜黄素实现的紫外线到蓝光阻断透明纤维素膜。

Seeking materials from nature for interrupting eye damage: Ultraviolet to blue light blocking clear cellulose films enabled by curcumin.

机构信息

College of Light Industry and Textiles, Qiqihar University, Qiqihar 161006, Heilongjiang Province, China.

College of Light Industry and Textiles, Qiqihar University, Qiqihar 161006, Heilongjiang Province, China.

出版信息

Int J Biol Macromol. 2024 Nov;279(Pt 2):135325. doi: 10.1016/j.ijbiomac.2024.135325. Epub 2024 Sep 3.

Abstract

The harms caused by ultraviolet (UV) and blue light to eyes are attracting momentous concern due to growing exposure to artificial illumination and modern IT devices. Herein, a simple and eco-friendly adsorption approach was employed to integrate curcumin, a natural bioactive compound, into the cellulose substrate for the development of flexible and biodegradable filters capable of blocking harmful light. The curcumin/cellulose films demonstrate excellent UV-screening competence and photostability, with UV-A and UV-B screening ratios ranging from 92.8 % to 100 % and 89.2 % to 100 %, respectively. The films could block >96 % of blue light in the wavelength range of 400-500 nm. Meanwhile, the films maintain high transmittance (85.2-89.4 %) and low haze (2.0-2.7 %). The films can efficiently block blue light emanated from sunlight, light-emitting diodes, lighting systems, computer and mobile phone screens. Encouragingly, the incorporation of curcumin led to a substantial increase in the water contact angle, elevating it from 41.6 to 81.3°. Furthermore, the films exhibit excellent antimicrobial properties, biodegradability, and tensile strength in excess of 72 MPa. Therefore, these films fabricated entirely from natural resources have the potential to achieve practical applications such as food packaging and spectacle lens, especially suitable for electronic screen protectors.

摘要

由于人工照明和现代 IT 设备的日益普及,紫外线 (UV) 和蓝光对眼睛造成的危害引起了人们的极大关注。在此,我们采用了一种简单且环保的吸附方法,将天然生物活性化合物姜黄素整合到纤维素基底中,开发出了具有柔性和可生物降解特性的过滤器,可阻挡有害光线。姜黄素/纤维素薄膜表现出优异的紫外线屏蔽性能和光稳定性,其紫外线-A 和紫外线-B 的屏蔽率分别为 92.8%至 100%和 89.2%至 100%。这些薄膜可以阻挡波长在 400-500nm 范围内的超过 96%的蓝光。同时,这些薄膜保持高透光率(85.2-89.4%)和低雾度(2.0-2.7%)。这些薄膜可以有效地阻挡来自阳光、发光二极管、照明系统、计算机和手机屏幕的蓝光。令人鼓舞的是,姜黄素的加入导致水接触角显著增加,从 41.6°增加到 81.3°。此外,这些薄膜还具有出色的抗菌性能、生物降解性和超过 72MPa 的拉伸强度。因此,这些完全由天然资源制成的薄膜具有实现实际应用的潜力,例如食品包装和眼镜镜片,特别适合用作电子屏幕保护装置。

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