Designing a flower-shaped ZnS/CoS heterojunction for efficient electroreduction of N to NH.
作者信息
Gao Ze, Xu Ming, Liu Renming, Xu Hang, Chu Dongxue, Yang Daming, Feng Ming, Wang Ting, Jin Guangyong
机构信息
Jilin Key Laboratory of Solid-State Laser Technology and Application, School of Physics, Changchun University of Science and Technology, Changchun 130022, People's Republic of China.
Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130103, People's Republic of China.
出版信息
Chem Commun (Camb). 2024 Sep 26;60(78):10878-10881. doi: 10.1039/d4cc02860k.
The electrocatalytic nitrogen reduction reaction (NRR) is a highly promising process for synthesizing ammonia and holds great potential to replace the traditional Haber-Bosch process. Here, we report a novel flower-shaped ZnS/CoS composite electrocatalyst for the NRR. Remarkably, the ZnS/CoS-105 heterojunction catalyst achieved an NH yield rate of 20.42 μg h mg and a faradaic efficiency (FE) of 11.83% at -0.45 V RHE in an aqueous 0.1 M NaSO solution. In addition, ZnS/CoS-105 showed remarkable stability (up to 24 h) for the NRR process.
Zotero 插件