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用于增强光催化和废水修复的NiSe-ZnO纳米复合材料的简便合成

Facile synthesis of NiSe-ZnO nanocomposites for enhanced photocatalysis and wastewater remediation.

作者信息

Khan Sibghat Ullah, Hussain Rafaqat, Ali Zahid, Maryam Rabia, Hussain Afzal, Alajmi Mohamed Fahad, Rahman Shams Ur, Zulfiqar Sonia, Cochran Eric W

机构信息

Department of Physics, COMSATS University Islamabad Park Road Islamabad 45550 Pakistan

Department of Chemistry, COMSATS University Islamabad Park Road Islamabad 45550 Pakistan.

出版信息

RSC Adv. 2024 Sep 9;14(39):28626-28637. doi: 10.1039/d4ra04715j. eCollection 2024 Sep 4.

Abstract

In this study, NiSe nanocubes, ZnO rods, and their composites were prepared by simple chemical methods to investigate their photocatalytic response and antibacterial activity. The optimal concentration of NiSe nanocubes was explored for enhanced photocatalytic performance by varying its percentage in the NiSe-ZnO composites. The findings suggested that the optical response of ZnO was significantly improved and shifted towards visible region by incorporating NiSe as a co-catalyst. The photocatalytic properties of NiSe, ZnO, and NiSe-ZnO composites were assessed under visible light by using methylene blue (MB) as a model pollutant. The results showed that the optimized composite containing 75% NiSe with ZnO exhibited outstanding photocatalytic efficiency of 97%. The degradation of MB dye by NiSe, ZnO, and their composites followed the pseudo-first-order reaction kinetics (Langmuir-Hinshelwood model). Furthermore, the prepared NiSe-ZnO composite displayed exceptional reusability and stability over a number of cycles, demonstrating its practical applicability. This research presents unique findings, showcasing the comparative antibacterial performance of NiSe, ZnO, and NiSe-ZnO nanocomposites against (). Of all the prepared photocatalysts, the 75% NiSe-ZnO nanocomposite revealed the best performance, exhibiting an inhibition zone of 28 mm.

摘要

在本研究中,通过简单的化学方法制备了硒化镍纳米立方体、氧化锌棒及其复合材料,以研究它们的光催化响应和抗菌活性。通过改变硒化镍 - 氧化锌复合材料中硒化镍的百分比,探索了其增强光催化性能的最佳浓度。研究结果表明,通过引入硒化镍作为助催化剂,氧化锌的光学响应得到显著改善,并向可见光区域移动。以亚甲基蓝(MB)为模型污染物,在可见光下评估了硒化镍、氧化锌和硒化镍 - 氧化锌复合材料的光催化性能。结果表明,含75%硒化镍与氧化锌的优化复合材料表现出97%的出色光催化效率。硒化镍、氧化锌及其复合材料对MB染料的降解遵循准一级反应动力学(朗缪尔 - 欣谢尔伍德模型)。此外,制备的硒化镍 - 氧化锌复合材料在多个循环中表现出优异的可重复使用性和稳定性,证明了其实际应用价值。本研究呈现了独特的发现,展示了硒化镍、氧化锌和硒化镍 - 氧化锌纳米复合材料对()的抗菌性能比较。在所有制备的光催化剂中,75%的硒化镍 - 氧化锌纳米复合材料表现出最佳性能,抑菌圈为28毫米。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e59c/11381969/b02eb9b50d61/d4ra04715j-f1.jpg

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