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新型水热合成 Ag/Mn-ZnO 纳米材料对有毒有机化合物的快速光降解和对细菌的光抑制作用。

Rapid photodegradation of toxic organic compounds and photo inhibition of bacteria in the presence of novel hydrothermally synthesized Ag/Mn-ZnO nanomaterial.

机构信息

Institute of Chemical Sciences, Gomal University, D. I. Khan, KP, Pakistan.

Department of Chemistry, Faculty of Science, University of Tabuk, Tabuk, 71491, Saudi Arabia.

出版信息

Environ Res. 2023 Aug 15;231(Pt 1):116093. doi: 10.1016/j.envres.2023.116093. Epub 2023 May 12.

Abstract

Purified water is the most concerning issue these days, and utmost conventional practices are allied with various downsides. Therefore, an ecologically benign and easily amicable therapeutic approach is the requirement. In this wonder, nanometer phenomena bring an innovative change to the material world. It has the potential to produce nanosized materials for wide-ranging applications. The subsequent research highlights the synthesis of Ag/Mn-ZnO nanomaterial via a one-pot hydrothermal route with an efficient photocatalytic activity against organic dyes and bacteria. The outcomes revealed that the size of the particle (4-5 nm) and dispersion of spherically shaped silver nanoparticles intensely affected by employing Mn-ZnO as a support material. Use of silver NPs as a dopant activates the active sites of the support medium and provides a higher surface area to upsurge the degradation rate. The synthesized nanomaterial was evaluated against photocatalytic activity using Methyl orange and alizarin red as model dyes and confided that more than 70% of both the dyes degraded under 100 min duration. It is well recognize that the modified nanomaterial recreates an essential role in every light-based reaction, and virtually produced highly reactive oxygen species. The synthesized nanomaterial was also evaluated against E. coli bacterium both in light and dark. The zone of inhibition in the presence of Ag/Mn-ZnO was observed both in light (18 ± 0.2 mm) and dark (12 ± 0.4 mm). The hemolytic activity shows that Ag/Mn-ZnO has very low toxicity. Hence, the prepared Ag/Mn-ZnO nanomaterial might be an effective tool against the depletion of further harmful environmental pollutants and microbes.

摘要

纯化水是目前最令人关注的问题,大多数常规方法都存在各种缺点。因此,需要一种生态友好且易于实施的治疗方法。在这个奇迹中,纳米现象为物质世界带来了创新性的变化。它有可能为广泛的应用生产纳米级材料。随后的研究强调了通过一锅水热途径合成 Ag/Mn-ZnO 纳米材料,该材料具有对有机染料和细菌的高效光催化活性。结果表明,通过使用 Mn-ZnO 作为支撑材料,粒子(4-5nm)的尺寸和球形银纳米粒子的分散度发生了强烈变化。银 NPs 的使用作为掺杂剂激活了支撑介质的活性位点,并提供了更高的表面积以提高降解率。使用甲基橙和茜素红作为模型染料评估合成的纳米材料的光催化活性,发现两种染料在 100 分钟内降解率超过 70%。众所周知,修饰后的纳米材料在每一个基于光的反应中都起着至关重要的作用,并实际上产生了高反应性的氧物质。还在光照和黑暗条件下对大肠杆菌进行了合成纳米材料的评估。在 Ag/Mn-ZnO 的存在下观察到抑菌区,在光照下(18±0.2mm)和黑暗下(12±0.4mm)均有抑菌区。溶血活性表明 Ag/Mn-ZnO 具有很低的毒性。因此,制备的 Ag/Mn-ZnO 纳米材料可能是一种有效工具,可以减少进一步的有害环境污染物和微生物的消耗。

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