School of Food Science and Bioengineering, Changsha University of Science and Technology, Changsha 410114, China; Hunan Province Prepared Dishes Engineering Technology Research Center, Changsha University of Science & Technology, Changsha 410114, China.
School of Food Science and Bioengineering, Changsha University of Science and Technology, Changsha 410114, China.
Int J Biol Macromol. 2024 Oct;278(Pt 4):135281. doi: 10.1016/j.ijbiomac.2024.135281. Epub 2024 Sep 10.
Particle concentrations (w) and oil content (Φ) are crucial factors influencing the gel stability of Pickering emulsions. To understand the stabilization mechanism comprehensively, we prepared emulsion gels stabilized by CNF/DMY composite particles at various w (0.5-1.5 wt%) and Φ (0.2-0.6, v/v). The microstructure revealed the adsorption of these particles at the oil-water interface, with excess particles forming a three-dimensional network structure in the continuous phase. Rheological studies showed that the network structure of Pickering emulsions was significantly influenced by w and Φ, resulting in improved emulsion gel strength that hindered the movement of oil droplets and oxygen in the continuous phase, thereby enhancing emulsion stability. Three scenarios for the critical strain (γ) were observed: at Φ = 0.2, γ decreased with increasing w, while at Φ = 0.4, γ increased with increasing w. At Φ = 0.6, γ remained relatively constant regardless of w. In conclusion, adjusting particle concentration and oil content enabled the control of microstructure, rheological properties, and antioxidant capacity of emulsion gels. These findings could be a valuable resource for formulating and ensuring the quality of emulsion gel-based products in the food industry.
颗粒浓度 (w) 和含油率 (Φ) 是影响 Pickering 乳液凝胶稳定性的关键因素。为了全面了解稳定机制,我们制备了由 CNF/DMY 复合颗粒稳定的乳液凝胶,w 值 (0.5-1.5 wt%) 和 Φ 值 (0.2-0.6,v/v) 不同。微观结构揭示了这些颗粒在油水界面的吸附,过量的颗粒在连续相中形成了三维网络结构。流变学研究表明,Pickering 乳液的网络结构受到 w 和 Φ 的显著影响,从而提高了乳液凝胶的强度,阻碍了油滴和连续相中的氧气的运动,从而提高了乳液的稳定性。观察到临界应变 (γ) 的三种情况:在 Φ=0.2 时,γ 随 w 的增加而减小,而在 Φ=0.4 时,γ 随 w 的增加而增加。在 Φ=0.6 时,γ 不受 w 的影响基本保持不变。总之,调节颗粒浓度和含油率可以控制乳液凝胶的微观结构、流变性能和抗氧化能力。这些发现可为食品工业中乳液凝胶基产品的配方和质量保证提供有价值的信息。