Tailored MXene-derived nano-heterostructure oxides for peroxymonosulfate activation in the treatment of municipal wastewaters.

Nowadays, in the field of environmental protection, a huge effort is focused on efficient and sustainable processes to treat wastewaters. The current study emphasizes the photocatalytic performance of TiNbO, a nano-heterostructure material derived from the oxidation of (TiNb)CT MXene. The TiNbO nano-heterostructure exhibited remarkable performance in the degradation of caffeine (CAF) and sulfamethoxazole (SMX) under UVA irradiation in the presence of peroxymonosulfate (PMS). Under optimal conditions, 0.2 g L of TiNbO, 0.5 mM PMS and 50 μM concentration of pollutants and natural pH of deionized water, we observed a complete degradation of SMX and 91% degradation of CAF. Scavenging studies provided evidence for the involvement of ˙OH and SO˙ in the degradation of the pollutants, which was also supported by indirect techniques of electron paramagnetic resonance (EPR) spectroscopy. The degradation pathway of the pollutants was analyzed by liquid chromatography-mass spectrometry (LC-MS) and several mechanisms were suggested including hydroxylation and isoxazole ring-opening reactions. In addition, X-ray photoelectron spectroscopy (XPS) supported the proposed degradation mechanism. The reusability test underscored the high stability and efficiency of TiNbO. Moreover, the significance of this research was emphasized by conducting degradation studies in tap water (TW) and tertiary effluents of the wastewater (WW) treatment plant in Bratislava. Under optimal conditions, 49% and 30% CAF were degraded in TW and WW, respectively, after 12 hours of reaction. For SMX, 68% and 67% degradations were obtained in TW and WW, respectively.