Concrete-based energy storage: exploring electrode and electrolyte enhancements.

The exploration of concrete-based energy storage devices represents a demanding field of research that aligns with the emerging concept of creating multifunctional and intelligent building solutions. The increasing need to attain zero carbon emissions and harness renewable energy sources underscores the importance of advancing energy storage technologies. A recent focus has been on structural supercapacitors, which not only store electrochemical energy but also support mechanical loads, presenting a promising avenue for research. We comprehensively review concrete-based energy storage devices, focusing on their unique properties, such as durability, widespread availability, low environmental impact, and advantages. First, we elucidate how concrete and its composites revolutionize basic building blocks for the design and fabrication of intrinsically strong structural materials. Afterward, we categorized concrete into two major parts of a supercapacitor, , electrode and electrolyte materials. We further describe the synthesis of concrete-based electrodes and electrolytes and highlight the main points to be addressed while synthesizing porous surface/electroactive matrices. The incorporation of carbon, polymers, metals, , enhances the energy density and durability of electrode materials. Furthermore, as an electrolyte, how concrete accommodates metal salts and the mode of diffusion/transport have been described. Although pure concrete electrolytes exhibit poor ionic conductivity, the addition of conducting polymers, metal/metal oxides, and carbon increases the overall performance of energy storage devices. At the end of the review, we discuss the challenges and perspectives on future research directions and provide overall conclusions.