Selective regulation of products for guaiacol hydrodeoxygenation by adjusting type and acidity of supports.

Upgrading lignin-oil into advanced fuels or chemicals has been widely studied in recent years. To understand the effect of support type and acidity on the hydrodeoxygenation (HDO) of guaiacol (lignin-oil model compound), Ni-based catalysts were prepared with SiO, AlO and ZSM-5 as supports, respectively. The catalysts were characterized by X-ray diffraction (XRD), N adsorption desorption, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and Pyridine adsorption Fourier-transform infrared (Py-IR). The research results indicate that selective regulation of guaiacol hydrogenation products can be achieved by changing the type and acidity of support. Cyclohexanol is the main product over Ni/SiO, while cyclohexane is the main product over Ni/ZSM-5 series catalysts. Moreover, as the Si/Al ratio increases, the catalytic activity of Ni/ZSM-5 slightly decreases, and the yield of cyclohexane also decreases. The Brønsted acidity of the support is the key to promoting the conversion of cyclohexanol to cyclohexane. The formation of NiAlO is the main reason for the relatively low activity of Ni/AlO. The conversion of guaiacol is as high as 99.2 %, and the yield of cyclohexane is as high as 86.6 % over Ni/ZSM-5(Si/Al = 27). In addition, complete conversion of guaiacol and 92.6 % yield of cyclohexanol were achieved over Ni/SiO. More importantly, Ni/SiO and Ni/ZSM-5(27) are suitable for aromatic substrates with different substituents, respectively.