芳基环烷烃的电化学解构官能团化——阳极生成的芳族自由基阳离子的碎片化
Electrochemical deconstructive functionalization of arylcycloalkanes fragmentation of anodically generated aromatic radical cations.
作者信息
Maashi Hussain A, Husayni Abdulrahman H, Harnedy James, Morrill Louis C
机构信息
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Department of Chemistry, College of Science, University of Bisha, Bisha 61922, Saudi Arabia.
出版信息
Chem Commun (Camb). 2024 Oct 3;60(80):11190-11201. doi: 10.1039/d4cc03279a.
This highlight summarises electrochemical approaches for the deconstructive functionalization of arylcycloalkanes the fragmentation of anodically generated aromatic radical cations. A diverse range of deconstructive functionalization processes is described, including discussion on the electrochemical reaction conditions employed, scope and limitations, and reaction mechanisms, in addition to highlighting future opportunities in this burgeoning area of sustainable synthesis.
本亮点总结了用于芳基环烷烃解构官能化的电化学方法——阳极生成的芳族自由基阳离子的碎片化。描述了各种解构官能化过程，除了强调可持续合成这一新兴领域的未来机遇外，还讨论了所采用的电化学反应条件、范围和局限性以及反应机理。
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