Coherent Ultrafast Stimulated X-Ray Raman Spectroscopy of Dissipative Conical Intersections.

The quantum coherent dynamics of a vibronic wave packet in a molecule passing through a conical intersection can be revealed using attosecond transient coherent Raman spectroscopy. In particular, the time evolution of the electronic coherence can be monitored in the presence of vibrational dynamics. So far, the technique has been investigated without including environmental quantum noise. Here, we employ the numerically exact hierarchy equation of motion approach to show that the transient coherent Raman signals are robust and accessible on times of up to a few hundred femtoseconds with respect to electonic and vibrational dephasing.