School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, PR China.
School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, PR China; State Key Laboratory of Bio-Fibers and Eco-Textiles (Qingdao University), Qingdao 266071, PR China.
Int J Biol Macromol. 2024 Nov;279(Pt 4):135467. doi: 10.1016/j.ijbiomac.2024.135467. Epub 2024 Sep 12.
In order to improve the dispersion of molybdenum disulfide (MoS) and enhance the performance of MoS, two alginate-derived biomass carbon-MoS (BC-MoS) composites: CMB/CMS, were prepared by introducing BC during the synthesis of MoS by hydrothermal. The effects of different gels, times and temperatures of the synthesized BC-MoS were investigated, and the adsorption capacity for methylene blue (MB), basic fuchsin (BF) and copper ions (Cu) was tested. The results indicated that the vertical growth of MoS on the BC surface could be realized when using xero-gel, while the BC and MoS were mixed uniformly when using wet-gel. Compared with MoS, the hydrophilicity and water dispersibility of BC-MoS were greatly improved, and BC-MoS had better adsorption capacity for MB/BF/Cu (99.61/86.83/60 mg/g). The adsorption mechanism exhibits that the adsorption force of BC-MoS on MB/BF is mainly based on the electrostatic force, and the adsorption on Cu comes from the electrostatic force and the Lewis soft-soft interaction. This study dramatically enriches the application of transition metal chalcogenides and provides a meaningful reference for wastewater treatment.
为了提高二硫化钼(MoS)的分散性并增强其性能,通过水热法合成 MoS 时引入生物质碳(BC),制备了两种海藻酸钠衍生的生物质碳-MoS(BC-MoS)复合材料:CMB/CMS。考察了不同凝胶、合成 BC-MoS 的时间和温度的影响,并测试了对亚甲基蓝(MB)、碱性品红(BF)和铜离子(Cu)的吸附能力。结果表明,使用干凝胶时可以实现 MoS 在 BC 表面的垂直生长,而使用湿凝胶时 BC 和 MoS 均匀混合。与 MoS 相比,BC-MoS 的亲水性和水分散性得到了极大的提高,对 MB/BF/Cu 的吸附能力也更强(99.61/86.83/60mg/g)。吸附机制表明,BC-MoS 对 MB/BF 的吸附力主要基于静电力,而对 Cu 的吸附则来自静电力和路易斯软-软相互作用。本研究极大地丰富了过渡金属硫属化合物的应用,并为废水处理提供了有意义的参考。