Yadav Manisha, Singh Nagender, Khan Suhail Ayoub, Raorane Chaitany Jayprakash, Shin Dong Kil
Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.
Department of Fashion and Apparel Engineering, The Technological Institute of Textile and Sciences, Bhiwani 127021, India.
Polymers (Basel). 2024 Aug 26;16(17):2417. doi: 10.3390/polym16172417.
This review embarks on a comprehensive journey, exploring the application of lignocellulosic biomass materials as highly effective adsorbents for the removal of textile dyes (cationic and anionic dyes) from wastewater. A literature review and analysis were conducted to identify existing gaps in previous research on the use of lignocellulosic biomass for dye removal. This study investigates the factors and challenges associated with dye removal methods and signifies their uses. The study delves into the pivotal role of several parameters influencing adsorption, such as contact time, pH, concentration, and temperature. It then critically examines the adsorption isotherms, unveiling the equilibrium relationship between adsorbent and dye and shedding light on the mechanisms of their interaction. The adsorption process kinetics are thoroughly investigated, and a detailed examination of the adsorbed rate of dye molecules onto lignocellulosic biomass materials is carried out. This includes a lively discussion of the pseudo-first, pseudo-second, and intra-particle diffusion models. The thermodynamic aspects of the adsorption process are also addressed, elucidating the feasibility and spontaneity of the removal process under various temperature conditions. The paper then dives into desorption studies, providing insights into the regeneration potential of lignocellulosic biomass materials for sustainable reusability. The environmental impact and cost-effectiveness of employing lignocellulosic biomass materials in textiles including Congo Red, Reactive Black 5, Direct Yellow 12, Crystal Violet, Malachite Green, Acid Yellow 99, and others dyes from wastewater treatment are discussed, emphasizing the significance of eco-friendly solutions. In summary, this review brings together a wealth of diverse studies and findings to present a comprehensive overview of lignocellulosic biomass materials as adsorbents for textile cationic and anionic dye removal, encompassing various aspects from influential parameters to kinetics, adsorption isotherms, desorption, and thermodynamics studies. Its scope and other considerations are also discussed along with its benefits. The collective knowledge synthesized in this paper is intended to contribute to the advancement of sustainable and efficient water treatment technologies in the textile industry.
本综述开启了一段全面的探索之旅,探讨木质纤维素生物质材料作为高效吸附剂用于去除废水中纺织染料(阳离子和阴离子染料)的应用。通过文献综述和分析,找出以往关于使用木质纤维素生物质去除染料研究中存在的差距。本研究调查了与染料去除方法相关的因素和挑战,并阐明了它们的用途。该研究深入探讨了影响吸附的几个关键参数的作用,如接触时间、pH值、浓度和温度。然后,对吸附等温线进行了批判性研究,揭示了吸附剂与染料之间的平衡关系,并阐明了它们相互作用的机制。对吸附过程动力学进行了全面研究,并详细考察了染料分子在木质纤维素生物质材料上的吸附速率。这包括对拟一级、拟二级和颗粒内扩散模型的热烈讨论。还讨论了吸附过程的热力学方面,阐明了在各种温度条件下去除过程的可行性和自发性。接着,论文深入进行了解吸研究,深入了解木质纤维素生物质材料可持续重复使用的再生潜力。讨论了在纺织品中使用木质纤维素生物质材料处理包括刚果红、活性黑5、直接黄12、结晶紫、孔雀石绿、酸性黄99等染料废水的环境影响和成本效益,强调了环保解决方案的重要性。总之,本综述汇集了大量不同的研究和发现,全面概述了木质纤维素生物质材料作为吸附剂用于去除纺织阳离子和阴离子染料的情况,涵盖了从影响参数到动力学、吸附等温线、解吸和热力学研究等各个方面。还讨论了其范围、其他考虑因素及其益处。本文综合的知识旨在推动纺织行业可持续高效水处理技术的发展。