Efficient Removal of Mercury from Wastewater Solutions by a Nitrogen-Doped Hyper-Crosslinked Polyamine.

Mercury, a highly toxic metal and pollutant, poses a significant risk to human health and the environment. This study describes the synthesis of a new nitrogen-doped heteroaromatic hyper-crosslinked polyamine () via the polycondensation of 2,6-diaminopyrazine and tris(4-formylphenyl)amine for the efficient removal of mercury ions from aqueous solutions. The polymer was characterized by solid-state C-NMR and FT-IR spectroscopy. A powder X-ray diffraction and thermogravimetric analysis showed that the polymer was semicrystalline in nature and stable up to 500 °C. Adsorption isotherms indicated that mercury adsorption occurred via mono- and multilayer adsorption by , as depicted by the Langmuir, Freundlich, and Redlich-Peterson isotherm models, with a maximum adsorption capacity of = 333.3 mg/g. Adsorption kinetic models suggested that the adsorption process was fast and effective, reaching equilibrium within 20 min. Thermodynamics of the adsorption process revealed that it was endothermic and spontaneous in nature due to the positive Δ of 48 kJ/mol and negative Δ values of -4.5 kJ/mol at 293 K. Wastewater treatment revealed 98% removal of mercury indicating the selective nature of . Finally, exhibited excellent performance and regeneration up to three cycles, demonstrating its great potential as an adsorbent for environmental remediation applications.