Study on Grouting Performance Optimization of Polymer Composite Materials Applied to Water Plugging and Reinforcement in Mines.

With the increasing drilling depth of mines, the cross-complexity of fissures in the rock body, and the frequent occurrence of sudden water surges, polymer slurry, with its advantages of good permeability and strong water plugging, is increasingly used in mine grouting projects. Additional research is needed in order to further improve the grouting performance of polymer slurry, ensure the safety of mining operations, and reduce the grouting cost. In this paper, a polymer composite grouting material was prepared with diphenyl methyl diisocyanate, polyether polyol, and fly ash, as the main raw materials, with coupling agent and catalyst as auxiliary reagents. The performance of the composite grouting material in terms of mechanical properties, thermal stability, hydrophobicity, and bonding was explored. This study's findings indicated that incorporating fly ash led to notable enhancements in the thermal stability and water resistance of the polymer slurry. Furthermore, the introduction of fly ash notably raised the starting degradation temperature of the polymer, boosted the water contact angle of the composite material, and reduced the density and reaction temperature of the composite material. In addition, the catalyst and coupling agent as auxiliary reagents affected the polymers in terms of mechanical properties; in this paper, dibutyltin dilaurate was used as the catalyst, and organosilanes were used as the coupling agent. The catalyst successfully sped up the polymer's gel time, however, an excessive quantity of catalyst compromised the polymer's mechanical characteristics. The addition of organosilanes has a positive effect on the dynamic mechanical properties of the composites, fracture toughness, compression, bending, and bond strength. The research can offer a theoretical direction for creating polymer mixtures in mine grouting projects.