Shao Zhen-Wu, Xiong Chaozhi, Yang Jiajie, Mei Zhewei, Xiong Li, Wu Wenjing, Liu Chong
School of Chemical Engineering, Sichuan University, Chengdu, 610065, China.
Chem Commun (Camb). 2024 Oct 1;60(79):11100-11103. doi: 10.1039/d4cc03895a.
A highly crystalline and robust Zr-hydroxamate metal-organic framework (MOF) was prepared from a pyrazine-based ligand, featuring abundant ,' chelating sites. High-degree Pd(II) metalation of the MOF was achieved through straightforward postsynthetic modification, with detailed coordination chemistry elucidated spectroscopically. The Pd-functionalized MOF was then studied as a heterogeneous Suzuki-Miyaura catalyst, through combined experimental/computational methods.
一种高度结晶且坚固的锆异羟肟酸金属有机框架（MOF）由一种基于吡嗪的配体制备而成，具有丰富的螯合位点。通过直接的后合成修饰实现了MOF的高度钯（II）金属化，并通过光谱学阐明了详细的配位化学。然后通过实验/计算相结合的方法，将钯功能化的MOF作为非均相铃木-宫浦催化剂进行了研究。
