Encapsulation of Bamboosa vulgaris culms derived activated biochar into hierarchical permeable, phosphate rich and functionalized alginate aerogel composites and its contribution in U(VI) adsorption.

In this study, a facile methodology was designed to encapsulate Bamboosa vulgaris culms derived activated biochar (BVC) in a variable mass ratio, into a three-dimensional hierarchical porous and permeable and amino-thiocarbamated alginate (TSC) to prepare hybrid biosorbents (BVC-MSA). These ultralight and lyophilized phosphate rich macroporous sorbents were rationally characterized through FTIR, XRD, BET, SEM-EDS, elemental mapping, XPS techniques and employed for efficient UO adsorption from aqueous solutions. The phytic acid (PA) was found to be a suitable hydrophilic and phosphorylating agent for the TSC matrix through hydrogen-bonded crosslinking when employed in a correct mass ratio (1:3). The SEM-EDS and XPS analyses confirmed the UO sorption onto BVC-MSA-3 (the most suitable composite with a BVC/TSC mass ratio of 30.0 % w/w) and provided evidence of heteroatom involvement in developing the physico-chemical interactions. The BCV-MSA-3 exhibited the best response as a sorbent during kinetics/sorption process, therefore, it was selected to study the equilibrium sorption studies. The BCV-MSA-3 removal efficiency increased from 12.1 to 94.2 % using 0.2 to 1.8 g/L sorbent dose at pH (4.5). The mentioned sorbent displayed a significant maximum sorption capacity q (309.55 mg/g at 35 °C) calculated through the best-fitted Langmuir and Temkin models (R ≈ 0.99). The sorption kinetics followed the pseudo-second-order (PSORE) model and exhibited fast sorption rate t (180 min). Thermodynamic parameters clarified that the sorption process is feasible ΔG (-25.3 to -27.6 kJ/mol kJ/mol), endothermic ΔH (27.17 kJ/mol), and proceeds with a positive entropy (0.176 kJ/mol.K). The study shows that BCV-MSA-3 could be an alternative and auspicious sorbent for uranium removal from aqueous solution.