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用于能量存储的复合相变材料(CPCM)的热性能和机械性能评估。

Thermal and mechanical performance assessment of composite (CPCM) for energy storage.

作者信息

Khalaf Alshammari Naif, Trigui Abdelwaheb, Hassani Rym

机构信息

Mechanical Engineering Department, Engineering college, University of Ha'il, Hail, 8148, Saudi Arabia.

Laboratory of Multifunctional Materials and Applications (LaMMa), Faculty of Sciences of Sfax, Tunisia.

出版信息

Heliyon. 2024 Aug 31;10(17):e37212. doi: 10.1016/j.heliyon.2024.e37212. eCollection 2024 Sep 15.

Abstract

Phase change materials (PCMs) face obstacles in being widely used due to issues with heat transfer and maintaining their shape. In this research, instead of using binders, the Hexadecane (H) is melted in such a way that the capillary forces of the molten wax allow it to be impregnated into the low-density polyethylene (P) molecules and bind it together as a composite. It was found that the hot melt extrusion (HME) combines the two materials at the micro-scale, forming a phase change composite (CPCM) with various geometries that possesses superior latent heat and shape stability during phase transition. The structure can incorporate a higher percentage of PCM (60 %) using this method, which also results in lower costs. According to the thermal analysis, (H60P40) provides great thermal stability and can store a lot of energy per unit of weight. It has a high capacity of storing latent heat at 129.56 J/g and can also prevent Hexadecane leakage. Based on the mechanical properties results, hexadecane acts like plasticizer thus the addition of PCM decreases Young's modulus, stress in break, and stress at yield. This trend is observed as the PCM content increases. The high values of elongation at break also indicates the strong plasticizing properties of PCM. Based on the obtained results, the CPCMs as a potential candidate for an application in buildings for thermal regulation, reducing energy consumption, and reducing indoor temperature swing.

摘要

相变材料(PCM)由于传热和形状保持方面的问题,在广泛应用中面临障碍。在本研究中,十六烷(H)不是使用粘合剂,而是以这样一种方式熔化,即熔化蜡的毛细作用力使其能够浸渍到低密度聚乙烯(P)分子中,并将它们结合在一起形成复合材料。研究发现,热熔挤出(HME)在微观尺度上使两种材料结合,形成具有各种几何形状的相变复合材料(CPCM),该复合材料在相变过程中具有优异的潜热和形状稳定性。使用这种方法,该结构可以包含更高百分比的PCM(60%),这也降低了成本。根据热分析,(H60P40)具有良好的热稳定性,每单位重量可以储存大量能量。它具有129.56J/g的高潜热储存能力,还可以防止十六烷泄漏。根据力学性能结果,十六烷起到增塑剂的作用,因此PCM的添加会降低杨氏模量、断裂应力和屈服应力。随着PCM含量的增加,观察到这种趋势。高断裂伸长率值也表明PCM具有很强的增塑性能。基于获得的结果,CPCM作为一种潜在的候选材料,可应用于建筑物的热调节、降低能耗和减少室内温度波动。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98af/11403539/319ca0ade029/ga1.jpg

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