用于喹喔啉-2(1)-酮烷基化的光激发硝基芳烃。
Photoexcited nitroarenes for alkylation of quinoxalin-2(1)-ones.
作者信息
Wu Lingang, Wang Zhaoxue, Qiao Yanling, Xie Lei, Wang Qingmin
机构信息
School of Chemistry and Chemical Engineering, School of Pharmaceutical Sciences and Food Engineering, Liaocheng University, Liaocheng 252000, Shandong, People's Republic of China.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
出版信息
Chem Commun (Camb). 2024 Oct 3;60(80):11311-11314. doi: 10.1039/d4cc04315d.
A straightforward method for the dehydrogenative alkylation of quinoxalin-2(1)-ones with alkylbenzenes has been developed, facilitated by a photoexcited nitroarene. The reaction's success hinges on the dual role of the photoexcited nitroarene molecule, acting as both a hydrogen atom transfer (HAT) reagent and an oxidant. This technique is both atom-economical and cost-effective, due to the readily available nitroarene, which serves as the sole intermediary in the reaction process.
已开发出一种用烷基苯对喹喔啉-2(1)-酮进行脱氢烷基化的直接方法，该方法由光激发的硝基芳烃促进。该反应的成功取决于光激发的硝基芳烃分子的双重作用，它既作为氢原子转移（HAT）试剂又作为氧化剂。由于反应过程中用作唯一中间体的硝基芳烃易于获得，该技术具有原子经济性且成本效益高。
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