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用于光控液滴和气泡运动的仿生透明滑面

Biomimetic Transparent Slippery Surface for the Locomotion of Photocontrol Droplets and Bubbles.

作者信息

Yu Anhui, Guo Zhiguang

机构信息

Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062, P. R. China.

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, P. R. China.

出版信息

Small. 2024 Nov;20(48):e2405878. doi: 10.1002/smll.202405878. Epub 2024 Sep 27.

Abstract

Directed transportation and collection of liquids and bubbles play a vital role in the survival of ecosystems. Among them, the optical response control is widely used in the fields of microfluidic chips and chemical synthesis because of its high remote operation and fast response speed. However, due to poor light transmission, the development direction of traditional near-infrared (NIR) absorbing materials in the field of visualization is limited, and there are few reports of manufacturing an operating platform that can realize the directional movement of droplets/bubbles on a single platform. Here, a transparent photo-responsive PBFS platform is prepared for droplet and bubble manipulation by coating the etched glass substrate with Prussian blue (PB) nanocubes. When near-infrared (NIR) irradiation on the PBFS platform, PB nanocubes trigger heat production by photothermal means, due to the action of Marangoni force, the surface tension on the left and right sides of the droplets and bubbles is not uniform, forming a surface tension gradient, thereby driving the movement of the droplets and bubbles. The control platform has good application potential in the field of microchemical reaction and biomedical engineering and brings new solutions to the field of transparent photothermal materials.

摘要

液体和气泡的定向运输与收集对生态系统的生存起着至关重要的作用。其中,光学响应控制因其高远程操控性和快速响应速度而在微流控芯片和化学合成领域得到广泛应用。然而,由于光传输性能不佳,传统近红外(NIR)吸收材料在可视化领域的发展方向受到限制,关于制造一个能在单一平台上实现液滴/气泡定向移动的操作平台的报道很少。在此,通过在蚀刻玻璃基板上涂覆普鲁士蓝(PB)纳米立方体,制备了一个用于液滴和气泡操控的透明光响应PBFS平台。当近红外(NIR)照射在PBFS平台上时,PB纳米立方体通过光热手段触发产热,由于马兰戈尼力的作用,液滴和气泡左右两侧的表面张力不均匀,形成表面张力梯度,从而驱动液滴和气泡移动。该控制平台在微化学反应和生物医学工程领域具有良好的应用潜力,为透明光热材料领域带来了新的解决方案。

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