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自然老化对生物炭理化性质及 Cd(II)迁移性的影响。

Effect of natural aging on biochar physicochemical property and mobility of Cd (II).

机构信息

Institute of Resources, Environment and Soil Fertilizer, Fujian Academy of Agricultural Sciences, Fuzhou, 350003, Fujian, China.

Fujian Province Key Laboratory of Agro-Ecological Processes in Hilly Red Soil, Fuzhou, 350003, Fujian, China.

出版信息

Sci Rep. 2024 Sep 27;14(1):22214. doi: 10.1038/s41598-024-72771-8.

Abstract

This project utilized both field experiment and laboratory analyses to address the gap in understanding regarding the alterations in properties and functions of biochar, and the impact of heavy metal passivation in soil over long-term natural field aging. The study aimed to examine the changes in the physical and chemical characteristics of biochar over an extended period of natural aging. Additionally, it sought to analyze the impact and mechanisms of biochar in reducing of the harmful effects of the heavy metal cadmium (Cd) during the aging process. Both original and aged biochar conformed to the pseudo-second-order kinetics model and the Langmuir model. The aging process enhanced the adsorption of Cd by biochar and mitigated the leaching of Cd into the soil. These findings provide a scientific basis for evaluating biochar's environmental behavior and its potential use in the remediation of soil contaminated with heavy metals.

摘要

本项目利用田间试验和实验室分析,解决了在长期自然田间老化过程中,生物炭性质和功能的变化以及重金属钝化对土壤的影响方面理解上的差距。该研究旨在考察生物炭在自然老化过程中物理化学特性的变化。此外,还分析了生物炭在减轻重金属镉(Cd)在老化过程中有害影响的作用机制。原始和老化的生物炭都符合伪二级动力学模型和朗缪尔模型。老化过程增强了生物炭对 Cd 的吸附,并减轻了 Cd 向土壤中的浸出。这些发现为评估生物炭的环境行为及其在修复重金属污染土壤方面的潜在应用提供了科学依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d093/11436867/66289f4d5bd2/41598_2024_72771_Fig1_HTML.jpg

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