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激光熔覆Ni60-WC复合涂层的微观结构与摩擦学性能实验研究

Experimental Study on the Microstructure and Tribological Properties of Laser-Clad Ni60-WC Composite Coatings.

作者信息

Cao Yupeng, Yan Kai, Shi Weidong, Zhou Rui, Li Bin, Qin Jiaxin

机构信息

School of Mechanical Engineering, Nantong University, Nantong 226019, China.

School of Information Science and Technology, Nantong University, Nantong 226019, China.

出版信息

Materials (Basel). 2024 Sep 21;17(18):4638. doi: 10.3390/ma17184638.

Abstract

To address the wear issues faced by the leg components of offshore platforms in harsh marine conditions, a Ni60-WC composite coating was fabricated on the surface of E690 high-strength steel using laser cladding. The microstructure, elemental distribution, microhardness, and tribological properties of the composite coating were characterized and tested using XRD (X-ray diffraction), SEM (scanning electron microscopy), EDS (energy-dispersive spectrometry), a microhardness tester, and a multifunctional tribometer. The study focused on the microstructure and tribological properties of the Ni60-WC composite coating. The results show that the composite coating primarily consists of γ-(Fe, Ni), WC, W2C, M23C6, and M6C phases, with cellular and dendritic structures at the top. WC and W2C, along with M23C6 and M6C, are precipitated from the W and C elements. The average hardness of the composite coating reached 569.5 HV, representing a 103% increase over the substrate hardness. The prepared composite coating exhibited a 32.6% increase in corrosion potential compared to the substrate. Additionally, the corrosion current density was reduced by 62.0%, indicating a significant enhancement in the corrosion resistance of the composite coating. The friction coefficient of the composite coating was reduced by 17.4% compared to the substrate, and wear volume was reduced by 79%, significantly enhancing the tribological performance of the coating due to reduced abrasive wear and fatigue wear.

摘要

为解决海上平台腿部部件在恶劣海洋环境下面临的磨损问题,采用激光熔覆在E690高强度钢表面制备了Ni60-WC复合涂层。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能谱仪(EDS)、显微硬度计和多功能摩擦磨损试验机对复合涂层的微观结构、元素分布、显微硬度和摩擦学性能进行了表征和测试。本研究聚焦于Ni60-WC复合涂层的微观结构和摩擦学性能。结果表明,复合涂层主要由γ-(Fe, Ni)、WC、W2C、M23C6和M6C相组成,顶部具有胞状和树枝状结构。WC和W2C以及M23C6和M6C由W和C元素析出。复合涂层的平均硬度达到569.5 HV,比基体硬度提高了103%。制备的复合涂层与基体相比,腐蚀电位提高了32.6%。此外,腐蚀电流密度降低了62.0%,表明复合涂层的耐腐蚀性显著提高。复合涂层的摩擦系数比基体降低了17.4%,磨损体积减少了79%,由于磨粒磨损和疲劳磨损的减少,涂层的摩擦学性能显著提高。

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